(2S,4aS,5R,8aR)-5-methyl-1-(4-toluenesulfonyl)-2-n-propyldecahydroquinoline

Base Information

Chemical Name:(2S,4aS,5R,8aR)-5-methyl-1-(4-toluenesulfonyl)-2-n-propyldecahydroquinoline
CAS No.:795275-79-5
Molecular Formula:C₂₀H₃₁NO₂S
Molecular Weight:349.538
Hs Code.:

Synonyms:(2S,4aS,5R,8aR)-5-methyl-1-(4-toluenesulfonyl)-2-n-propyldecahydroquinoline

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Chemical Property of (2S,4aS,5R,8aR)-5-methyl-1-(4-toluenesulfonyl)-2-n-propyldecahydroquinoline

Chemical Property:

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Technology Process of (2S,4aS,5R,8aR)-5-methyl-1-(4-toluenesulfonyl)-2-n-propyldecahydroquinoline

There total 4 articles about (2S,4aS,5R,8aR)-5-methyl-1-(4-toluenesulfonyl)-2-n-propyldecahydroquinoline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 795275-78-4
(4aS,5R,8aR)-5-Methyl-2-((E)-propenyl)-1-(toluene-4-sulfonyl)-decahydro-quinoline

: (2R,4aS,5R,8aR)-5-methyl-1-(4-toluenesulfonyl)-2-n-propyldecahydroquinoline

: 795275-79-5
(2S,4aS,5R,8aR)-5-methyl-1-(4-toluenesulfonyl)-2-n-propyldecahydroquinoline

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethanol; at 20 ℃; under 33752.7 Torr;
DOI:10.1016/j.tet.2004.06.148

Reference yield:

: 795275-76-2
2-[(1R,2S,3R)-2-allyl-3-methylcyclohexyl]-1H-isoindole-1,3(2H)-dione

: 795275-79-5
(2S,4aS,5R,8aR)-5-methyl-1-(4-toluenesulfonyl)-2-n-propyldecahydroquinoline

Guidance literature:: Multi-step reaction with 4 steps

1: hydrazine hydrate; 1-hexene / ethanol / Heating

2: 95 percent / Et₃N / CH₂Cl₂ / 60 h / 20 °C

3: Pd(OAc)3; P(o-Tol)3; Na₂CO₃ / n-Bu₄NCl / acetonitrile / 68 h / 86 °C

4: 26 mg / H₂ / Pd/C / ethanol / 20 °C / 33752.7 Torr

With 1-hexene; palladium(III) acetate; hydrogen; sodium carbonate; hydrazine hydrate; triethylamine; tris-(o-tolyl)phosphine; palladium on activated charcoal; tetrabutyl-ammonium chloride; In ethanol; dichloromethane; acetonitrile; 3: Heck reaction;
DOI:10.1016/j.tet.2004.06.148

Reference yield:

: 795275-73-9
N-[(1R,2S,3R)-2-allyl-3-methylcyclohexyl]-4-toluenesulfonamide

: 795275-79-5
(2S,4aS,5R,8aR)-5-methyl-1-(4-toluenesulfonyl)-2-n-propyldecahydroquinoline

Guidance literature:: Multi-step reaction with 2 steps

1: Pd(OAc)3; P(o-Tol)3; Na₂CO₃ / n-Bu₄NCl / acetonitrile / 68 h / 86 °C

2: 26 mg / H₂ / Pd/C / ethanol / 20 °C / 33752.7 Torr

With palladium(III) acetate; hydrogen; sodium carbonate; tris-(o-tolyl)phosphine; palladium on activated charcoal; tetrabutyl-ammonium chloride; In ethanol; acetonitrile; 1: Heck reaction;
DOI:10.1016/j.tet.2004.06.148