Toluene-4-sulfonic acid (S)-2-[(1R,4R)-4-((R)-6-benzyloxy-4-methyl-hexyl)-cyclopent-2-enyl]-propyl ester

Base Information

Chemical Name:Toluene-4-sulfonic acid (S)-2-[(1R,4R)-4-((R)-6-benzyloxy-4-methyl-hexyl)-cyclopent-2-enyl]-propyl ester
CAS No.:600167-88-2
Molecular Formula:C₂₉H₄₀O₄S
Molecular Weight:484.7
Hs Code.:

Synonyms:Toluene-4-sulfonic acid (S)-2-[(1R,4R)-4-((R)-6-benzyloxy-4-methyl-hexyl)-cyclopent-2-enyl]-propyl ester

Suppliers and Price of Toluene-4-sulfonic acid (S)-2-[(1R,4R)-4-((R)-6-benzyloxy-4-methyl-hexyl)-cyclopent-2-enyl]-propyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Toluene-4-sulfonic acid (S)-2-[(1R,4R)-4-((R)-6-benzyloxy-4-methyl-hexyl)-cyclopent-2-enyl]-propyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Toluene-4-sulfonic acid (S)-2-[(1R,4R)-4-((R)-6-benzyloxy-4-methyl-hexyl)-cyclopent-2-enyl]-propyl ester

There total 7 articles about Toluene-4-sulfonic acid (S)-2-[(1R,4R)-4-((R)-6-benzyloxy-4-methyl-hexyl)-cyclopent-2-enyl]-propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1117-61-9
(3R)-citronellol

: 600167-88-2
Toluene-4-sulfonic acid (S)-2-[(1R,4R)-4-((R)-6-benzyloxy-4-methyl-hexyl)-cyclopent-2-enyl]-propyl ester

Guidance literature:: Multi-step reaction with 6 steps

1.1: NaH / 1,2-dimethoxy-ethane / 4 h / Heating

2.1: O₃

2.2: NaBH₄ / methanol; CH₂Cl₂ / 12 h / -78 - 20 °C

3.1: PPh₃; CBr₄ / diethyl ether / 12 h / 20 °C

4.1: Mg / tetrahydrofuran / 65 °C

4.2: CuBr*SMe₂ / tetrahydrofuran / -78 °C

4.3: 80 percent / tetrahydrofuran / 12 h / -78 - 20 °C

5.1: LiAlH₄ / tetrahydrofuran / 65 °C

6.1: pyridine / 0 °C

With pyridine; lithium aluminium tetrahydride; carbon tetrabromide; sodium hydride; ozone; magnesium; triphenylphosphine; In tetrahydrofuran; 1,2-dimethoxyethane; diethyl ether;
DOI:10.1002/anie.200250629

Reference yield:

: 100-39-0
benzyl bromide

: 600167-88-2
Toluene-4-sulfonic acid (S)-2-[(1R,4R)-4-((R)-6-benzyloxy-4-methyl-hexyl)-cyclopent-2-enyl]-propyl ester

Guidance literature:: Multi-step reaction with 6 steps

1.1: NaH / 1,2-dimethoxy-ethane / 4 h / Heating

2.1: O₃

2.2: NaBH₄ / methanol; CH₂Cl₂ / 12 h / -78 - 20 °C

3.1: PPh₃; CBr₄ / diethyl ether / 12 h / 20 °C

4.1: Mg / tetrahydrofuran / 65 °C

4.2: CuBr*SMe₂ / tetrahydrofuran / -78 °C

4.3: 80 percent / tetrahydrofuran / 12 h / -78 - 20 °C

5.1: LiAlH₄ / tetrahydrofuran / 65 °C

6.1: pyridine / 0 °C

With pyridine; lithium aluminium tetrahydride; carbon tetrabromide; sodium hydride; ozone; magnesium; triphenylphosphine; In tetrahydrofuran; 1,2-dimethoxyethane; diethyl ether;
DOI:10.1002/anie.200250629

Reference yield:

: 83541-12-2
(R)-(+)-citronellyl benzyl ether

: 600167-88-2
Toluene-4-sulfonic acid (S)-2-[(1R,4R)-4-((R)-6-benzyloxy-4-methyl-hexyl)-cyclopent-2-enyl]-propyl ester

Guidance literature:: Multi-step reaction with 5 steps

1.1: O₃

1.2: NaBH₄ / methanol; CH₂Cl₂ / 12 h / -78 - 20 °C

2.1: PPh₃; CBr₄ / diethyl ether / 12 h / 20 °C

3.1: Mg / tetrahydrofuran / 65 °C

3.2: CuBr*SMe₂ / tetrahydrofuran / -78 °C

3.3: 80 percent / tetrahydrofuran / 12 h / -78 - 20 °C

4.1: LiAlH₄ / tetrahydrofuran / 65 °C

5.1: pyridine / 0 °C

With pyridine; lithium aluminium tetrahydride; carbon tetrabromide; ozone; magnesium; triphenylphosphine; In tetrahydrofuran; diethyl ether;
DOI:10.1002/anie.200250629