trans-chlorobis(methyldiphenylphosphine)phenylplatinum(II)

Base Information

• Chemical Name: trans-chlorobis(methyldiphenylphosphine)phenylplatinum(II)
• CAS No.: 60772-01-2
• Molecular Formula: C₃₂H₃₁ClP₂Pt
• Molecular Weight: 708.079
• Mol file: 60772-01-2.mol

Synonyms:trans-chlorobis(methyldiphenylphosphine)phenylplatinum(II)

Chemical Property of trans-chlorobis(methyldiphenylphosphine)phenylplatinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-chlorobis(methyldiphenylphosphine)phenylplatinum(II)

There total 7 articles about trans-chlorobis(methyldiphenylphosphine)phenylplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

cis-dichlorobis(methyldiphenylphosphine)platinum(II) (16633-72-0,53585-56-1,60103-85-7) + diphenylmercury(II) (587-85-9,1337-09-3) → trans-chlorobis(methyldiphenylphosphine)phenylplatinum(II) (60772-01-2)

Guidance literature:

In ethanol; byproducts: PhHgCl2; stoich. amts.; refluxing (N2-atmosphere, 24 h); solvent removal, sublimation off of PhHgCl (90°C/0.001 Torr, 12 h), crystn. (C6H6/light petroleum); elem. anal.;

DOI:10.1039/DT9790001246

Reference yield:

platinum(II)(Cl)(η3-allyl)(diphenylmethylphosphine) (71035-51-3) + trimethyl(phenyl)stannane (934-56-5) → sym-{platinum(phenyl)(μ-Cl)(diphenylmethylphosphine)}2 + trans-chlorobis(methyldiphenylphosphine)phenylplatinum(II) (60772-01-2) + trimethyltin(IV)chloride (1066-45-1)

Guidance literature:

In chloroform-d1; Under N2, soln. is sealed in an MMR-tube, in less than 1 d complete conversion to PtPh(c3H5)(PMePh2), which is disapeared after 1 month.; Monitored by NMR, fractional recrystn. yields mixt. of sym-trans/cis(Pt2Ph2Cl2(PMePh2)2), evapn. of mother liquor yields trans-PtClPh(PMePh2)2.;

Reference yield:

phenylchloro(1,5-cyclooctadiene)platinum(II) + diphenyl(methyl)phosphine (1486-28-8) → trans-chlorobis(methyldiphenylphosphine)phenylplatinum(II) (60772-01-2)

Guidance literature:

In chloroform-d1; soln. of org. compd. in CDCl3 added to suspn. of Pt complex in CDCl3, mixture stirred for 30 min; product not isolated, detected by NMR;

DOI:10.1021/ic50225a005

upstream raw materials:

diphenyl(methyl)phosphine

carbonylchloro(methyldiphenylphosphine)phenylplatinum(II)

platinum(II)(Cl)(η3-allyl)(diphenylmethylphosphine)

trimethyl(phenyl)stannane

Downstream raw materials:

Pt(OH)Ph(PMePh₂)2

trans-[Pt(Ph)(CO)(PMePh₂)2][CF₃SO₃]

(Pt(C₆H₅)(P(CH₃)(C₆H₅)2)3)⁽¹⁺⁾