1-((4-O-acetyloxy-5-methyl)-2,3,6-trideoxy-β-L-erythro-hex-2-enopyranosyl)-1-phenylethanone

Base Information

Chemical Name:1-((4-O-acetyloxy-5-methyl)-2,3,6-trideoxy-β-L-erythro-hex-2-enopyranosyl)-1-phenylethanone
CAS No.:115093-65-7
Molecular Formula:C₁₆H₁₈O₄
Molecular Weight:274.317
Hs Code.:

Synonyms:1-((4-O-acetyloxy-5-methyl)-2,3,6-trideoxy-β-L-erythro-hex-2-enopyranosyl)-1-phenylethanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-((4-O-acetyloxy-5-methyl)-2,3,6-trideoxy-β-L-erythro-hex-2-enopyranosyl)-1-phenylethanone

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Technology Process of 1-((4-O-acetyloxy-5-methyl)-2,3,6-trideoxy-β-L-erythro-hex-2-enopyranosyl)-1-phenylethanone

There total 3 articles about 1-((4-O-acetyloxy-5-methyl)-2,3,6-trideoxy-β-L-erythro-hex-2-enopyranosyl)-1-phenylethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 13735-81-4
1-styrenyloxytrimethylsilane

: 34819-86-8
3,4-di-O-acetyl-6-deoxy-L-glucal

: 115093-65-7
1-((4-O-acetyloxy-5-methyl)-2,3,6-trideoxy-β-L-erythro-hex-2-enopyranosyl)-1-phenylethanone

Guidance literature:: With gadolinium(III) trifluoromethanesulfonate; In acetonitrile; at 20 - 40 ℃; diastereoselective reaction; Catalytic behavior;
DOI:10.1016/j.tet.2015.11.002

Reference yield: 49.0%

: 98-86-2
acetophenone

: 34819-86-8
3,4-di-O-acetyl-6-deoxy-L-glucal

: 115093-65-7
1-((4-O-acetyloxy-5-methyl)-2,3,6-trideoxy-β-L-erythro-hex-2-enopyranosyl)-1-phenylethanone

Guidance literature:: acetophenone; With t-butyldimethylsiyl triflate; N-ethyl-N,N-diisopropylamine; In dichloromethane; for 0.333333h; Inert atmosphere;

3,4-di-O-acetyl-6-deoxy-L-glucal; In dichloromethane; at 0 - 30 ℃; Inert atmosphere;
DOI:10.1016/j.carres.2016.11.018

Reference yield:

: 13735-81-4
1-styrenyloxytrimethylsilane

: 34819-86-8
3,4-di-O-acetyl-6-deoxy-L-glucal

: 115093-66-8
α-1-(4'-acetoxy-2',3',6'-trideoxy-D-threo-hex-2'-enopyranosyl)acetophenone

: 115093-65-7
1-((4-O-acetyloxy-5-methyl)-2,3,6-trideoxy-β-L-erythro-hex-2-enopyranosyl)-1-phenylethanone

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at -45 - 20 ℃; Yield given. Yields of byproduct given;
DOI:10.1021/jo00251a011