2-[2-(hydroxyimino)-2-phenylethyl]disulfanyl-1-phenyl-1-ethanone oxime

Base Information

• Chemical Name: 2-[2-(hydroxyimino)-2-phenylethyl]disulfanyl-1-phenyl-1-ethanone oxime
• CAS No.: 23080-34-4
• Molecular Formula: C₁₆H₁₆N₂O₂S₂
• Molecular Weight: 332.447
• Mol file: 23080-34-4.mol

Synonyms:2-[2-(hydroxyimino)-2-phenylethyl]disulfanyl-1-phenyl-1-ethanone oxime

Chemical Property of 2-[2-(hydroxyimino)-2-phenylethyl]disulfanyl-1-phenyl-1-ethanone oxime

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-[2-(hydroxyimino)-2-phenylethyl]disulfanyl-1-phenyl-1-ethanone oxime

There total 3 articles about 2-[2-(hydroxyimino)-2-phenylethyl]disulfanyl-1-phenyl-1-ethanone oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

2-(4,5-dihydro-1,3-thiazol-2-ylsulfanyl)-1-phenyl-1-ethanone (17385-78-3) → 2-[2-(hydroxyimino)-2-phenylethyl]disulfanyl-1-phenyl-1-ethanone oxime (23080-34-4)

Guidance literature:

With hydroxylamine hydrochloride; tetrabutylammomium bromide; sodium acetate; In 1,4-dioxane; water; at 20 ℃; for 72h;

DOI:10.1080/17415993.2010.533772

Reference yield:

α-bromoacetophenone (70-11-1) → 2-[2-(hydroxyimino)-2-phenylethyl]disulfanyl-1-phenyl-1-ethanone oxime (23080-34-4)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine / ethanol; N,N-dimethyl-formamide / 2 h

2: hydroxylamine hydrochloride; tetrabutylammomium bromide; sodium acetate / 1,4-dioxane; water / 72 h / 20 °C

With hydroxylamine hydrochloride; tetrabutylammomium bromide; sodium acetate; triethylamine; In 1,4-dioxane; ethanol; water; N,N-dimethyl-formamide;

DOI:10.1080/17415993.2010.533772

Reference yield:

→ 2-[2-(hydroxyimino)-2-phenylethyl]disulfanyl-1-phenyl-1-ethanone oxime (23080-34-4)

Guidance literature:

2-Mercapto-acetophenon-oxim, I2;

upstream raw materials:

2-(4,5-dihydro-1,3-thiazol-2-ylsulfanyl)-1-phenyl-1-ethanone

α-bromoacetophenone