methyl 2,3,4-tri-O-acetyl-(2'-(4''-methylphenyl)-3'-(4'''-methoxybenzylaminocarbonyloxy)-1'-(E)-propenyloxy)-β-D-glucopyranosiduronate

Base Information

Chemical Name:methyl 2,3,4-tri-O-acetyl-(2'-(4''-methylphenyl)-3'-(4'''-methoxybenzylaminocarbonyloxy)-1'-(E)-propenyloxy)-β-D-glucopyranosiduronate
CAS No.:676606-12-5
Molecular Formula:C₃₂H₃₇NO₁₃
Molecular Weight:643.645
Hs Code.:

Synonyms:methyl 2,3,4-tri-O-acetyl-(2'-(4''-methylphenyl)-3'-(4'''-methoxybenzylaminocarbonyloxy)-1'-(E)-propenyloxy)-β-D-glucopyranosiduronate

Suppliers and Price of methyl 2,3,4-tri-O-acetyl-(2'-(4''-methylphenyl)-3'-(4'''-methoxybenzylaminocarbonyloxy)-1'-(E)-propenyloxy)-β-D-glucopyranosiduronate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 2,3,4-tri-O-acetyl-(2'-(4''-methylphenyl)-3'-(4'''-methoxybenzylaminocarbonyloxy)-1'-(E)-propenyloxy)-β-D-glucopyranosiduronate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 2,3,4-tri-O-acetyl-(2'-(4''-methylphenyl)-3'-(4'''-methoxybenzylaminocarbonyloxy)-1'-(E)-propenyloxy)-β-D-glucopyranosiduronate

There total 2 articles about methyl 2,3,4-tri-O-acetyl-(2'-(4''-methylphenyl)-3'-(4'''-methoxybenzylaminocarbonyloxy)-1'-(E)-propenyloxy)-β-D-glucopyranosiduronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 2393-23-9
4-methoxy-benzylamine

: 676606-09-0
methyl 2,3,4-tri-O-acetyl-(2'-(4''-methylphenyl)-3'-(O-phenylcarbonyloxy)-1'-(E)-propenyloxy)-β-D-glucopyranosiduronate

: 676606-12-5
methyl 2,3,4-tri-O-acetyl-(2'-(4''-methylphenyl)-3'-(4'''-methoxybenzylaminocarbonyloxy)-1'-(E)-propenyloxy)-β-D-glucopyranosiduronate

Guidance literature:: With dmap; In acetonitrile; at 20 ℃; for 24h;
DOI:10.1016/j.bmc.2003.11.026

Reference yield:

: 21085-72-3
1-bromo-2,3,4-tri-O-acetyl-α-D-glucuronic acid methyl ester

: 676606-12-5
methyl 2,3,4-tri-O-acetyl-(2'-(4''-methylphenyl)-3'-(4'''-methoxybenzylaminocarbonyloxy)-1'-(E)-propenyloxy)-β-D-glucopyranosiduronate

Guidance literature:: Multi-step reaction with 4 steps

1: 54 percent / Ag₂O / acetonitrile / 3 h / 0 °C

2: 44 percent / NaBH₄; CeCl₃*7H₂O / methanol / 0.08 h

3: 78 percent / CH₂Cl₂ / 0.5 h / 0 °C

4: 65 percent / 4-dimethylaminopyridine / acetonitrile / 24 h / 20 °C

With dmap; sodium tetrahydroborate; cerium(III) chloride; silver(l) oxide; In methanol; dichloromethane; acetonitrile;
DOI:10.1016/j.bmc.2003.11.026