[(6-t-butyl-phenyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine)Cu(I)]B(C₆F₅)4

Base Information

• Chemical Name: [(6-t-butyl-phenyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine)Cu(I)]B(C₆F₅)4
• CAS No.: 943218-68-6
• Molecular Formula: C₂₄BF₂₀*C₂₈H₃₀N₄*Cu
• Molecular Weight: 1165.16
• Mol file: 943218-68-6.mol

Synonyms:[(6-t-butyl-phenyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine)Cu(I)]B(C₆F₅)4

Chemical Property of [(6-t-butyl-phenyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine)Cu(I)]B(C₆F₅)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(6-t-butyl-phenyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine)Cu(I)]B(C₆F₅)4

There total 1 articles about [(6-t-butyl-phenyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine)Cu(I)]B(C₆F₅)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

TBP-TMPA + tetrakis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate (425370-02-1) → [Cu(tbp-tmpa)][B(C6F5)4] (943218-68-6)

Guidance literature:

In diethyl ether; addn. of Cu complex to ligand in deoxygenated Et2O; slow pptn. in dry pentane under Ar;

DOI:10.1021/ja104107q

Reference yield: 85.0%

hydrogenchloride (7647-01-0,15364-23-5) + [(6-t-butyl-phenyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine)Cu(I)]B(C6F5)4 (943218-68-6) + oxygen (80937-33-3) → [(6-t-butyl-phenyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine)Cu(II)Cl]2(B(C6F5)4)2 + dihydrogen peroxide (7722-84-1)

Guidance literature:

In diethyl ether; under Ar; O2 bubbled through soln. of Cu complex in Et2O at -80°Cfor 10 s; excess O2 removed; HCl in Et2O added at -80°C; stirred for 30 min; warmed to room temp.; distd. H2O added; stirred at room temp. for 1 h; Et2O layer washed with pentane; ppt. recrystd. from THF-pentane; vac. dried; elem. anal.;

DOI:10.1021/ic702437c

Reference yield: 83.0%

chloroform (67-66-3,8013-54-5) + [(6-t-butyl-phenyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine)Cu(I)]B(C6F5)4 (943218-68-6) → [(6-t-butyl-phenyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine)Cu(II)Cl]2(B(C6F5)4)2

Guidance literature:

In tetrahydrofuran; under Ar; Cu complex dissolved in THF; stirred at room temp.; CHCl3 added; reacted for 2 h; pptd. by adding pentane; ppt. recrystd. from THF-pentane; vac. dried; elem. anal.;

DOI:10.1021/ic702437c

upstream raw materials:

tetrakis(acetonitrile)copper(I) tetrakis(pentafluorophenyl)borate

Downstream raw materials:

dihydrogen peroxide

[Cu(tbp-tmpa)(CO)][B(C₆F₅)4]

Refernces