4-CHLORO-2-METHOXYBENZYL ALCOHOL 97

Base Information

• Chemical Name: 4-CHLORO-2-METHOXYBENZYL ALCOHOL 97
• CAS No.: 55685-75-1
• Molecular Formula: C8H9ClO2
• Molecular Weight: 172.611
• Hs Code.: 2909499000
• European Community (EC) Number: 621-275-9
• Wikidata: Q106902758
• Mol file: 55685-75-1.mol

Synonyms:4-CHLORO-2-METHOXYBENZYL ALCOHOL 97;4-Chloro-alpha-methoxybenzenemethanol

Chemical Property of 4-CHLORO-2-METHOXYBENZYL ALCOHOL 97

Chemical Property:

• Vapor Pressure: 0.00386mmHg at 25°C
• Melting Point: 47-51 °C(lit.)
• Refractive Index: 1.548
• Boiling Point: 268.2 °C at 760 mmHg
• PKA: 12.12±0.20(Predicted)
• Flash Point: 116 °C
• PSA: 29.46000
• Density: 1.239g/cm³
• LogP: 1.84090
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 172.0291072
• Heavy Atom Count: 11
• Complexity: 119

Purity/Quality:

≥98% ^*data from raw suppliers

4-Chloro-2-methoxybenzyl alcohol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=C(C=CC(=C1)Cl)CO

Technology Process of 4-CHLORO-2-METHOXYBENZYL ALCOHOL 97

There total 3 articles about 4-CHLORO-2-METHOXYBENZYL ALCOHOL 97 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + 2,2,2-trichloro-1-(4-chlorophenyl)ethanone (27704-37-6) → Methyl 4-chlorobenzoate (1126-46-1) + 4-chlorobenzaldehyde methyl hemiacetal (55685-75-1)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/ejoc.201301170

Reference yield:

bromochlorobenzene (106-39-8) → Methyl 4-chlorobenzoate (1126-46-1) + 4-chlorobenzaldehyde methyl hemiacetal (55685-75-1)

Guidance literature:

Multi-step reaction with 2 steps

1.1: lithium chloride; magnesium / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

1.2: 0.5 h / 0 °C / Inert atmosphere

1.3: 2 h / 0 °C / Inert atmosphere

2.1: triethylamine / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

With magnesium; triethylamine; lithium chloride; In tetrahydrofuran;

DOI:10.1002/ejoc.201301170

Reference yield:

methanol (67-56-1) + 4-chlorobenzaldehyde (104-88-1) → 4-chlorobenzaldehyde methyl hemiacetal (55685-75-1)

Guidance literature:

In 1,4-dioxane; at 24.9 ℃; Equilibrium constant; Rate constant;

upstream raw materials:

methanol

4-chlorobenzaldehyde

2,2,2-trichloro-1-(4-chlorophenyl)ethanone

bromochlorobenzene

Downstream raw materials:

methanol

4-chlorobenzaldehyde

Methyl 4-chlorobenzoate

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 55685-75-1 4-CHLORO-2-METHOXYBENZYL ALCOHOL 97

Send

Send

Metric Ton KG G Pound L ML

Send

Send