2,4,5-tri-O-acetyl-3,6-benzyloxycarbonylimino-3,6-dideoxy-aldehydo-D-mannose

Base Information

Chemical Name:2,4,5-tri-O-acetyl-3,6-benzyloxycarbonylimino-3,6-dideoxy-aldehydo-D-mannose
CAS No.:91897-31-3
Molecular Formula:C₂₀H₂₃NO₉
Molecular Weight:421.404
Hs Code.:

Synonyms:2,4,5-tri-O-acetyl-3,6-benzyloxycarbonylimino-3,6-dideoxy-aldehydo-D-mannose

Suppliers and Price of 2,4,5-tri-O-acetyl-3,6-benzyloxycarbonylimino-3,6-dideoxy-aldehydo-D-mannose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,4,5-tri-O-acetyl-3,6-benzyloxycarbonylimino-3,6-dideoxy-aldehydo-D-mannose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,4,5-tri-O-acetyl-3,6-benzyloxycarbonylimino-3,6-dideoxy-aldehydo-D-mannose

There total 10 articles about 2,4,5-tri-O-acetyl-3,6-benzyloxycarbonylimino-3,6-dideoxy-aldehydo-D-mannose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 91897-30-2
(2S,3S,4R)-3,4-Diacetoxy-2-((S)-1-acetoxy-2,2-bis-ethylsulfanyl-ethyl)-pyrrolidine-1-carboxylic acid benzyl ester

: 91897-31-3
2,4,5-tri-O-acetyl-3,6-benzyloxycarbonylimino-3,6-dideoxy-aldehydo-D-mannose

Guidance literature:: With cadmium(II) carbonate; mercury dichloride; In water; acetone; for 1h; Heating;

Reference yield:

: 98237-78-6
((2R,3S,4S,5S,6S)-3,5-Dihydroxy-2-hydroxymethyl-6-methoxy-tetrahydro-pyran-4-yl)-carbamic acid benzyl ester

: 91897-31-3
2,4,5-tri-O-acetyl-3,6-benzyloxycarbonylimino-3,6-dideoxy-aldehydo-D-mannose

Guidance literature:: Multi-step reaction with 8 steps

1: pyridine / 36 h / Ambient temperature

2: H₂ / 10percent Pd/C / ethanol / 18 h / 3192 Torr

3: CH₃COONa / ethanol / 8 h / Heating

4: NaHCO₃ / ethanol; H₂O / 2 h / ice-cooling

5: 52 percent / aq. 0.4 M HCl / 16 h / 95 - 100 °C

6: 74 percent / conc. HCl / 0.25 h

7: 73 percent / pyridine

8: 96 percent / HgCl₂, CdCO₃ / H₂O; acetone / 1 h / Heating

With hydrogenchloride; cadmium(II) carbonate; hydrogen; sodium acetate; sodium hydrogencarbonate; mercury dichloride; palladium on activated charcoal; In pyridine; ethanol; water; acetone;

Reference yield:

: 91897-27-7
methyl 3-benzyloxycarbonylamino-3-deoxy-6-O-tosyl-α-D-mannopyranoside

: 91897-31-3
2,4,5-tri-O-acetyl-3,6-benzyloxycarbonylimino-3,6-dideoxy-aldehydo-D-mannose

Guidance literature:: Multi-step reaction with 7 steps

1: H₂ / 10percent Pd/C / ethanol / 18 h / 3192 Torr

2: CH₃COONa / ethanol / 8 h / Heating

3: NaHCO₃ / ethanol; H₂O / 2 h / ice-cooling

4: 52 percent / aq. 0.4 M HCl / 16 h / 95 - 100 °C

5: 74 percent / conc. HCl / 0.25 h

6: 73 percent / pyridine

7: 96 percent / HgCl₂, CdCO₃ / H₂O; acetone / 1 h / Heating

With hydrogenchloride; cadmium(II) carbonate; hydrogen; sodium acetate; sodium hydrogencarbonate; mercury dichloride; palladium on activated charcoal; In pyridine; ethanol; water; acetone;