Rh₂(C₅H₃N(P(C₆H₅)2)2)2(CO)2(CH₃OH)Cl⁽¹⁺⁾*PF₆^(1-)*CH₂Cl₂=Rh₂(C₅H₃N(P(C₆H₅)2)2)2(CO)2(CH₃OH)Cl(PF₆)*CH₂Cl₂

Base Information

• Chemical Name: Rh₂(C₅H₃N(P(C₆H₅)2)2)2(CO)2(CH₃OH)Cl⁽¹⁺⁾*PF₆^(1-)*CH₂Cl₂=Rh₂(C₅H₃N(P(C₆H₅)2)2)2(CO)2(CH₃OH)Cl(PF₆)*CH₂Cl₂
• CAS No.: 87555-70-2
• Molecular Formula: CH₂Cl₂*C₆₁H₅₀ClN₂O₃P₄Rh₂*F₆P
• Molecular Weight: 1454.14
• Mol file: 87555-70-2.mol

Synonyms:Rh₂(C₅H₃N(P(C₆H₅)2)2)2(CO)2(CH₃OH)Cl⁽¹⁺⁾*PF₆^(1-)*CH₂Cl₂=Rh₂(C₅H₃N(P(C₆H₅)2)2)2(CO)2(CH₃OH)Cl(PF₆)*CH₂Cl₂

Chemical Property of Rh₂(C₅H₃N(P(C₆H₅)2)2)2(CO)2(CH₃OH)Cl⁽¹⁺⁾*PF₆^(1-)*CH₂Cl₂=Rh₂(C₅H₃N(P(C₆H₅)2)2)2(CO)2(CH₃OH)Cl(PF₆)*CH₂Cl₂

Chemical Property:

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Technology Process of Rh₂(C₅H₃N(P(C₆H₅)2)2)2(CO)2(CH₃OH)Cl⁽¹⁺⁾*PF₆^(1-)*CH₂Cl₂=Rh₂(C₅H₃N(P(C₆H₅)2)2)2(CO)2(CH₃OH)Cl(PF₆)*CH₂Cl₂

There total 1 articles about Rh₂(C₅H₃N(P(C₆H₅)2)2)2(CO)2(CH₃OH)Cl⁽¹⁺⁾*PF₆^(1-)*CH₂Cl₂=Rh₂(C₅H₃N(P(C₆H₅)2)2)2(CO)2(CH₃OH)Cl(PF₆)*CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

methanol (67-56-1) + ammonium hexafluorophosphate + Rh4[μ-2,6-bis(diphenylphosphino)pyridine]2(μ-CO)(CO)2(μ-Cl)2Cl2 → di(rhodium)tetracarbonyl dichloride + chlorocarbonyl rhodium anion (15550-00-2,44516-52-1,108267-86-3) + Rh2(C5H3N(P(C6H5)2)2)2(CO)2(CH3OH)Cl(1+)*PF6(1-)*CH2Cl2=Rh2(C5H3N(P(C6H5)2)2)2(CO)2(CH3OH)Cl(PF6)*CH2Cl2 (87555-70-2)

Guidance literature:

With carbon monoxide; In chloroform; Rh complex treated with CO (1 atm) in CHCL3, NH4PF6 in CH3OH added;

DOI:10.1021/ja00361a054

upstream raw materials:

methanol