C₂₆H₃₃FO₄Si

Base Information

Chemical Name:C₂₆H₃₃FO₄Si
CAS No.:1209497-08-4
Molecular Formula:C₂₆H₃₃FO₄Si
Molecular Weight:456.63
Hs Code.:

C<sub>26</sub>H<sub>33</sub>FO<sub>4</sub>Si

Synonyms:C₂₆H₃₃FO₄Si

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Chemical Property of C₂₆H₃₃FO₄Si

Chemical Property:

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Technology Process of C₂₆H₃₃FO₄Si

There total 15 articles about C₂₆H₃₃FO₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 1209497-07-3
(3aR,6aR)-6-(tert-butyldiphenylsiloxymethyl)-5-fluoro-2,2,3a-trimethyl-3a,6a-dihydrocyclopenta[1,3]dioxol-4-one

: 1209497-08-4
C₂₆H₃₃FO₄Si

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; toluene; at -78 ℃; for 1h; stereoselective reaction;
DOI:10.1002/ejoc.201100062

Reference yield:

: C₂₅H₃₂O₄Si

: 1209497-08-4
C₂₆H₃₃FO₄Si

Guidance literature:: Multi-step reaction with 12 steps

1.1: dipyridinium dichromate / dichloromethane / 72 h / 20 °C / Molecular sieve

2.1: tetrahydrofuran / 0.5 h / -78 °C

2.2: 2 h / 20 °C

3.1: bromine / dichloromethane / 2 h / 20 °C

3.2: 0.33 h / 20 °C

3.3: 16 h / -78 - -30 °C

4.1: potassium carbonate / methanol / 12 h / 20 °C

5.1: N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid / 1,2-dichloro-ethane / -30 - 20 °C / Reflux

6.1: sodium methylate / methanol / 0.25 h / -30 - 0 °C

7.1: toluene-4-sulfonic acid; 2,2-dimethoxy-propane / 13 h / 20 °C

8.1: palladium 10% on activated carbon; hydrogen / ethyl acetate / 20 h / 760.05 Torr

9.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.25 h / -78 °C

10.1: sodium hydrogencarbonate; Selectfluor / acetonitrile / 1 h / 20 °C

11.1: lithium hexamethyldisilazane / tetrahydrofuran / 1.08 h / -78 - 0 °C

11.2: 0.25 h / 0 °C

11.3: 0.5 h / 0 °C

12.1: diisobutylaluminium hydride / dichloromethane; toluene / 1 h / -78 °C

With dipyridinium dichromate; palladium 10% on activated carbon; hydrogen; bromine; sodium methylate; diisobutylaluminium hydride; sodium hydrogencarbonate; potassium carbonate; toluene-4-sulfonic acid; Selectfluor; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; 2,2-dimethoxy-propane; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; 1,2-dichloro-ethane; toluene; acetonitrile;
DOI:10.1002/ejoc.201100062

Reference yield:

: 1209497-03-9
benzyl [(3aR,4S,6aS)-6a-(tert-butyldiphenylsiloxymethyl)-3a,6a-dihydro-2,2,4-trimethylcyclopenta[1,3]dioxol-4-yl] carbonate

: 1209497-08-4
C₂₆H₃₃FO₄Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: bromine / dichloromethane / 2 h / 20 °C

1.2: 0.33 h / 20 °C

1.3: 16 h / -78 - -30 °C

2.1: potassium carbonate / methanol / 12 h / 20 °C

3.1: N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid / 1,2-dichloro-ethane / -30 - 20 °C / Reflux

4.1: sodium methylate / methanol / 0.25 h / -30 - 0 °C

5.1: toluene-4-sulfonic acid; 2,2-dimethoxy-propane / 13 h / 20 °C

6.1: palladium 10% on activated carbon; hydrogen / ethyl acetate / 20 h / 760.05 Torr

7.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.25 h / -78 °C

8.1: sodium hydrogencarbonate; Selectfluor / acetonitrile / 1 h / 20 °C

9.1: lithium hexamethyldisilazane / tetrahydrofuran / 1.08 h / -78 - 0 °C

9.2: 0.25 h / 0 °C

9.3: 0.5 h / 0 °C

10.1: diisobutylaluminium hydride / dichloromethane; toluene / 1 h / -78 °C

With palladium 10% on activated carbon; hydrogen; bromine; sodium methylate; diisobutylaluminium hydride; sodium hydrogencarbonate; potassium carbonate; toluene-4-sulfonic acid; Selectfluor; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; 2,2-dimethoxy-propane; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; 1,2-dichloro-ethane; toluene; acetonitrile;
DOI:10.1002/ejoc.201100062