dichloro(tetramethylcyclopentadienylbenzene)iridium(III)dimer

Base Information

• Chemical Name: dichloro(tetramethylcyclopentadienylbenzene)iridium(III)dimer
• CAS No.: 1292280-39-7
• Molecular Formula: C₃₀H₃₄Cl₄Ir₂
• Molecular Weight: 920.852
• Mol file: 1292280-39-7.mol

Synonyms:dichloro(tetramethylcyclopentadienylbenzene)iridium(III)dimer

Chemical Property of dichloro(tetramethylcyclopentadienylbenzene)iridium(III)dimer

Chemical Property:

Purity/Quality:

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Technology Process of dichloro(tetramethylcyclopentadienylbenzene)iridium(III)dimer

There total 7 articles about dichloro(tetramethylcyclopentadienylbenzene)iridium(III)dimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

bis(1,5-cyclooctadiene)diiridium(I) dichloride (12112-67-3) + (2,3,4,5-tetramethylcyclopenta-2,4-dien-1-yl)-benzene (93768-83-3) → dichloro(tetramethylcyclopentadienylbenzene)iridium(III)dimer (1292280-39-7)

Guidance literature:

With hydrogenchloride; In methanol; at 115 ℃; for 1h; under 7757.43 Torr; Microwave irradiation;

DOI:10.1021/acs.organomet.6b00580

Reference yield: 58.5%

iridium(III) chloride trihydrate + (2,3,4,5-tetramethylcyclopenta-2,4-dien-1-yl)-benzene (93768-83-3) → dichloro(tetramethylcyclopentadienylbenzene)iridium(III)dimer (1292280-39-7)

Guidance literature:

In methanol; at 127 ℃; for 0.5h; under 20686.5 Torr; Microwave irradiation;

DOI:10.1039/d0dt00627k

Reference yield: 58.5%

iridium(III) chloride trihydrate + 1-phenyl-2,3,4,5-tetramethyl-1,3-cyclopentadiene (126910-37-0) → dichloro(tetramethylcyclopentadienylbenzene)iridium(III)dimer (1292280-39-7)

Guidance literature:

In methanol; at 127 ℃; for 30h; under 20686.5 Torr; Microwave irradiation;

DOI:10.1039/d0dt02408b

upstream raw materials:

1-phenyl-2,3,4,5-tetramethyl-1,3-cyclopentadiene

(2,3,4,5-tetramethylcyclopenta-2,4-dien-1-yl)-benzene

bis(1,5-cyclooctadiene)diiridium(I) dichloride

3-phenyl-1,2,4,5-tetramethyl-1,3-cyclopentadiene

Downstream raw materials:

[(η5-C5Me4C6H5)lrCI(bipy)]PF6

[Ir(η⁵‐Cp^ph)(phen)Cl]PF₆

[(η5-C5Me4C6H5)lr(dpq)Cl]PF6