tert-butyl 2-[(triisopropylsilyl)oxy]-6-(trimethylsilyl)phenylcarbamate

Base Information

Chemical Name:tert-butyl 2-[(triisopropylsilyl)oxy]-6-(trimethylsilyl)phenylcarbamate
CAS No.:398136-58-8
Molecular Formula:C₂₃H₄₃NO₃Si₂
Molecular Weight:437.77
Hs Code.:

Synonyms:tert-butyl 2-[(triisopropylsilyl)oxy]-6-(trimethylsilyl)phenylcarbamate

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Chemical Property of tert-butyl 2-[(triisopropylsilyl)oxy]-6-(trimethylsilyl)phenylcarbamate

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Technology Process of tert-butyl 2-[(triisopropylsilyl)oxy]-6-(trimethylsilyl)phenylcarbamate

There total 5 articles about tert-butyl 2-[(triisopropylsilyl)oxy]-6-(trimethylsilyl)phenylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 75-77-4
chloro-trimethyl-silane

: 194869-12-0
tert-butyl 2-((triisopropylsilyl)oxy)phenylcarbamate

: 398136-58-8
tert-butyl 2-[(triisopropylsilyl)oxy]-6-(trimethylsilyl)phenylcarbamate

Guidance literature:: tert-butyl 2-((triisopropylsilyl)oxy)phenylcarbamate; With tert.-butyl lithium; In diethyl ether; pentane; at -20 ℃; for 3h;

chloro-trimethyl-silane; In diethyl ether; pentane; at -95 - 20 ℃; Further stages.;
DOI:10.1021/ol016966c

Reference yield:

: 13154-24-0
triisopropylsilyl chloride

: 398136-58-8
tert-butyl 2-[(triisopropylsilyl)oxy]-6-(trimethylsilyl)phenylcarbamate

Guidance literature:: Multi-step reaction with 3 steps

1.1: 99 percent / imidazole / CH₂Cl₂ / 20 h / 20 °C

2.1: 80 percent / tetrahydrofuran / 48 h / Heating

3.1: t-BuLi / diethyl ether; pentane / 3 h / -20 °C

3.2: 62 percent / diethyl ether; pentane / -95 - 20 °C

With 1H-imidazole; tert.-butyl lithium; In tetrahydrofuran; diethyl ether; dichloromethane; pentane;
DOI:10.1021/ol016966c

Reference yield:

: 24424-99-5
di-tert-butyl dicarbonate

: 398136-58-8
tert-butyl 2-[(triisopropylsilyl)oxy]-6-(trimethylsilyl)phenylcarbamate

Guidance literature:: Multi-step reaction with 2 steps

1.1: 80 percent / tetrahydrofuran / 48 h / Heating

2.1: t-BuLi / diethyl ether; pentane / 3 h / -20 °C

2.2: 62 percent / diethyl ether; pentane / -95 - 20 °C

With tert.-butyl lithium; In tetrahydrofuran; diethyl ether; pentane;
DOI:10.1021/ol016966c