(2Z,6Z)-1-(tetrahydropyran-2-yloxy)-2,6-dimethyl-8-(p-tolylsulfonyl)octa-2,6-diene

Base Information

Chemical Name:(2Z,6Z)-1-(tetrahydropyran-2-yloxy)-2,6-dimethyl-8-(p-tolylsulfonyl)octa-2,6-diene
CAS No.:110547-84-7
Molecular Formula:C₂₂H₃₂O₄S
Molecular Weight:392.56
Hs Code.:

Synonyms:(2Z,6Z)-1-(tetrahydropyran-2-yloxy)-2,6-dimethyl-8-(p-tolylsulfonyl)octa-2,6-diene

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Chemical Property of (2Z,6Z)-1-(tetrahydropyran-2-yloxy)-2,6-dimethyl-8-(p-tolylsulfonyl)octa-2,6-diene

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Technology Process of (2Z,6Z)-1-(tetrahydropyran-2-yloxy)-2,6-dimethyl-8-(p-tolylsulfonyl)octa-2,6-diene

There total 15 articles about (2Z,6Z)-1-(tetrahydropyran-2-yloxy)-2,6-dimethyl-8-(p-tolylsulfonyl)octa-2,6-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: C₁₅H₂₅BrO₂

: 657-84-1
sodium tosylate

: 1393475-07-4
C₂₂H₃₂O₄S

: 110547-84-7
(2Z,6Z)-1-(tetrahydropyran-2-yloxy)-2,6-dimethyl-8-(p-tolylsulfonyl)octa-2,6-diene

Guidance literature:: In N,N-dimethyl-formamide; acetonitrile; at 20 ℃; for 6h; Cooling with ice; Inert atmosphere;
DOI:10.1021/ja306184m

Reference yield:

: 86636-47-7
(2Z,6Z)-8-(benzyloxy)-2,6-dimethyl-1-(tetrahydropyran-2-yloxy)-octa-2,6-diene

: 110547-84-7
(2Z,6Z)-1-(tetrahydropyran-2-yloxy)-2,6-dimethyl-8-(p-tolylsulfonyl)octa-2,6-diene

Guidance literature:: Multi-step reaction with 3 steps

1: 89 percent / Na, NH₃ / 0.17 h / -60 °C

2: MeSO₂Cl, LiCl, s-collidine / dimethylformamide / 2 h / 0 °C

3: dimethylformamide / Ambient temperature

With 2,4,6-trimethyl-pyridine; ammonia; sodium; methanesulfonyl chloride; lithium chloride; In N,N-dimethyl-formamide;
DOI:10.1039/c39860001761

Reference yield:

: 110547-85-8
(2Z,6Z)-3,7-Dimethyl-8-(tetrahydropyran-2-yloxy)octa-2,6-dien-1-ol

: 110547-84-7
(2Z,6Z)-1-(tetrahydropyran-2-yloxy)-2,6-dimethyl-8-(p-tolylsulfonyl)octa-2,6-diene

Guidance literature:: Multi-step reaction with 2 steps

1: MeSO₂Cl, LiCl, s-collidine / dimethylformamide / 2 h / 0 °C

2: dimethylformamide / Ambient temperature

With 2,4,6-trimethyl-pyridine; methanesulfonyl chloride; lithium chloride; In N,N-dimethyl-formamide;
DOI:10.1039/c39860001761