(3R,4S,5R)-6-<(tert-Butyldiphenylsilyl)oxy>-3,4,5-tris<(trimethylsilyl)oxy>-N-methoxy-N-methylhexanamide

Base Information

Chemical Name:(3R,4S,5R)-6-<(tert-Butyldiphenylsilyl)oxy>-3,4,5-tris<(trimethylsilyl)oxy>-N-methoxy-N-methylhexanamide
CAS No.:172293-73-1
Molecular Formula:C₃₃H₅₉NO₆Si₄
Molecular Weight:678.177
Hs Code.:

Synonyms:(3R,4S,5R)-6-<(tert-Butyldiphenylsilyl)oxy>-3,4,5-tris<(trimethylsilyl)oxy>-N-methoxy-N-methylhexanamide

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Chemical Property of (3R,4S,5R)-6-<(tert-Butyldiphenylsilyl)oxy>-3,4,5-tris<(trimethylsilyl)oxy>-N-methoxy-N-methylhexanamide

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Technology Process of (3R,4S,5R)-6-<(tert-Butyldiphenylsilyl)oxy>-3,4,5-tris<(trimethylsilyl)oxy>-N-methoxy-N-methylhexanamide

There total 3 articles about (3R,4S,5R)-6-<(tert-Butyldiphenylsilyl)oxy>-3,4,5-tris<(trimethylsilyl)oxy>-N-methoxy-N-methylhexanamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 153321-80-3
(3R,4R,5R)-tert-butyl <6-(tert-butyldiphenylsilyloxy)-4,5-epoxy-3-hydroxy>hexanoate

: 172293-73-1
(3R,4S,5R)-6-<(tert-Butyldiphenylsilyl)oxy>-3,4,5-tris<(trimethylsilyl)oxy>-N-methoxy-N-methylhexanamide

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / Zn, (CH₃)3SiCl / CH₂Cl₂ / 0.03 h / Ambient temperature

2: AlMe₃ / CH₂Cl₂ / Ambient temperature; 1.) 30 min, 2.) 12 h

3: HMDS, pyridine / 3 h / Ambient temperature

With pyridine; chloro-trimethyl-silane; trimethylaluminum; 1,1,1,3,3,3-hexamethyl-disilazane; zinc; In dichloromethane;
DOI:10.1021/jo00127a047

Reference yield:

: 172293-71-9
(4R,5S,1'R)-5-<2'-<(tert-Butyldiphenylsilyl)oxy>-1'-hydroxyethyl>-4-hydroxy-2-oxo-1-oxacyclopentane

: 172293-73-1
(3R,4S,5R)-6-<(tert-Butyldiphenylsilyl)oxy>-3,4,5-tris<(trimethylsilyl)oxy>-N-methoxy-N-methylhexanamide

Guidance literature:: Multi-step reaction with 2 steps

1: AlMe₃ / CH₂Cl₂ / Ambient temperature; 1.) 30 min, 2.) 12 h

2: HMDS, pyridine / 3 h / Ambient temperature

With pyridine; trimethylaluminum; 1,1,1,3,3,3-hexamethyl-disilazane; In dichloromethane;
DOI:10.1021/jo00127a047