(η5-1,2-dihydropentalenyl)ruthemiun bis(triphenylphosphine)chloride

Base Information

Chemical Name:(η5-1,2-dihydropentalenyl)ruthemiun bis(triphenylphosphine)chloride
CAS No.:676530-44-2
Molecular Formula:C₄₄H₃₉ClP₂Ru
Molecular Weight:766.264
Hs Code.:

Synonyms:(η5-1,2-dihydropentalenyl)ruthemiun bis(triphenylphosphine)chloride

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Chemical Property of (η5-1,2-dihydropentalenyl)ruthemiun bis(triphenylphosphine)chloride

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Technology Process of (η5-1,2-dihydropentalenyl)ruthemiun bis(triphenylphosphine)chloride

There total 1 articles about (η5-1,2-dihydropentalenyl)ruthemiun bis(triphenylphosphine)chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 55102-19-7,879374-40-0,879374-44-4,99944-74-8
HRuCl(P(C₆H₅)3)3

: 5259-72-3,10060-40-9,111-78-4
cyclo-octa-1,5-diene

: 676530-44-2
(η5-1,2-dihydropentalenyl)ruthemiun bis(triphenylphosphine)chloride

Guidance literature:: In butanone; a mixt. of HRuCl(PPh3)3 and 1,5-cyclooctadiene in MEK was refluxed underN2 for 5 d; evapd. in vacuo, residue washed with hexane, ether, dissolved in CH2Cl2,passed through an alumina pad, eluate concd., layered with pentane, coo led at -20°C, crystals were collected;
DOI:10.1016/j.jorganchem.2003.09.052

Reference yield: 90.0%

: 676530-44-2
(η5-1,2-dihydropentalenyl)ruthemiun bis(triphenylphosphine)chloride

: 141-53-7
sodium formate

: [(η⁵-C₈H₉)Ru(PPh₃)₂H]

Guidance literature:: In methanol; for 4h; Schlenk technique; Inert atmosphere; Reflux;
DOI:10.1007/s11243-019-00337-z

Reference yield: 60.0%

: 676530-44-2
(η5-1,2-dihydropentalenyl)ruthemiun bis(triphenylphosphine)chloride

: 594-09-2
trimethylphosphane

: 1180663-43-7
RuDp(PPh₃)ClPMe₃

Guidance literature:: In toluene; (under N2, Schlenk); Ru-complex and ligand dissolved in toluene, heated at 35°C for 2 h; toluene evapd. under vac., ppt. dissolved in CH2Cl2, column chromy. on silica with CH2Cl2, dried under vac.; elem. anal.;
DOI:10.1021/om900075h