11-ethyliminodibenzyl

Base Information

• Chemical Name: 11-ethyliminodibenzyl
• CAS No.: 40583-88-8
• Molecular Formula: C₁₆H₁₇N
• Molecular Weight: 223.318
• Mol file: 40583-88-8.mol

Synonyms:11-ethyliminodibenzyl

Chemical Property of 11-ethyliminodibenzyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 11-ethyliminodibenzyl

There total 3 articles about 11-ethyliminodibenzyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

5-acetyliminodibenzyl (13080-75-6) → 9,10-dihydrodibenzazepine (494-19-9) + 11-ethyliminodibenzyl (40583-88-8) + ethanol (64-17-5)

Guidance literature:

With Mo₂(⁽¹⁾-H)2(OtBu)₆; diphenylsilane; In toluene; for 25h; Reagent/catalyst; Solvent; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1002/chem.201202857

Reference yield:

5-acetyliminodibenzyl (13080-75-6) → 9,10-dihydrodibenzazepine (494-19-9) + 11-ethyliminodibenzyl (40583-88-8)

Guidance literature:

With C₃₇H₅₄Cl₂N₂RhSi; phenylsilane; In toluene; at 20 ℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique;

DOI:10.1071/CH13196

Reference yield:

5-acetyliminodibenzyl (13080-75-6) → 11-ethyliminodibenzyl (40583-88-8) + ethanol (64-17-5)

Guidance literature:

With diphenylsilane; Mo₂(O-t-Bu)6; In toluene; at 111 ℃; for 25h; Reagent/catalyst; Solvent; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.201202857

upstream raw materials:

5-acetyliminodibenzyl

Downstream raw materials:

N-(2-(5-ethyl-10,11-dihydro-5H-dibenzo[b,f]azepin-2-yl)-2-phenylvinyl)-4-methylbenzenesulfonamide

N-(2-(5-ethyl-10,11-dihydro-5H-dibenzo[b,f]azepin-2-yl)-2-phenylvinyl)-4-methylbenzenesulfonamide

Refernces

• 1、 Krackl, Sebastian,Someya, Chika I.,Enthaler, Stephan. "Reductive cleavage of amides to alcohols and amines catalyzed by well-defined bimetallic molybdenum complexes". supporting information. p. 15267 - 15271. Retrieved 2013/01/15.