(η5-cyclopentadienyl)bis(triphenylphosphane)(triflate)ruthenium(II)

Base Information

• Chemical Name: (η5-cyclopentadienyl)bis(triphenylphosphane)(triflate)ruthenium(II)
• CAS No.: 113322-93-3
• Molecular Formula: C₄₂H₃₅F₃O₃P₂RuS
• Molecular Weight: 839.817

Synonyms:(η5-cyclopentadienyl)bis(triphenylphosphane)(triflate)ruthenium(II)

Chemical Property of (η5-cyclopentadienyl)bis(triphenylphosphane)(triflate)ruthenium(II)

Chemical Property:

Purity/Quality:

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Technology Process of (η5-cyclopentadienyl)bis(triphenylphosphane)(triflate)ruthenium(II)

There total 3 articles about (η5-cyclopentadienyl)bis(triphenylphosphane)(triflate)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8) + trifluorormethanesulfonic acid (1493-13-6) + silver trifluoromethanesulfonate (2923-28-6) + triphenylphosphine (603-35-0) → [ruthenium(II)(Cl)(cyclopentadienyl)(triphenylphosphine)2](OTs) (113322-93-3)

Guidance literature:

In pentan-1-ol; toluene; under Ar atm.; Ru complex, Ag salt, PPh3, Ag salt, CF3SO3H charged into react. vessel, flushed with Ar, degassed, dry toluene added, stirred for5 min, amyl alcohol added, stirred at 60°C for 5 min; cooled to room temp., concd. in vacuo;

DOI:10.1016/j.jcat.2010.04.002

Reference yield: 90.0%

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8) + silver trifluoromethanesulfonate (2923-28-6) + dimethylfumarate (624-49-7) → (η5-cyclopentadienyl)bis(triphenylphosphane)(triflate)ruthenium(II) (113322-93-3) + Ru(C5H5)(P(C6H5)3)2(CH3OCOCH)2(1+)*CF3SO3(1-)=[Ru(C5H5)(P(C6H5)3)2(CH3OCOCH)2](CF3SO3)

Guidance literature:

In tetrahydrofuran; N2, Schlenk techniques; Ru- and Ag-compd. stirring in solvent (20°C, 0.5 h), suspn. filtration, org. compd. addn., crystn. on hexane addn. (-80°C, 3 d); crystals washing (Et2O);

DOI:10.1016/0020-1693(95)04543-0

Reference yield: 75.0%

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8) + silver trifluoromethanesulfonate (2923-28-6) → (η5-cyclopentadienyl)bis(triphenylphosphane)(triflate)ruthenium(II) (113322-93-3)

Guidance literature:

In dichloromethane; byproducts: AgCl; straightforward react. in CH2Cl2; formed AgCl removed; hexane added to soln.; complex pptd.; ppt. recrystd. from CH2Cl2/hexane; elem. anal.;

DOI:10.1021/ja00215a071

upstream raw materials:

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

silver trifluoromethanesulfonate

dimethylfumarate

trifluorormethanesulfonic acid

Downstream raw materials:

{(C₅H₅)Ru(P(C₆H₅)3)2(SC₂H₄)}⁽¹⁺⁾*CF₃SO₃^(1-)*0.5CH₂Cl₂={(C₅H₅)Ru(P(C₆H₅)3)2(SC₂H₄)}(OSO₂CF₃)*0.5CH₂Cl₂

C₅H₅Ru(P(C₆H₅)3)2SH₂⁽¹⁺⁾*OSO₂CF₃^(1-)={C₅H₅Ru(P(C₆H₅)3)2SH₂}OSO₂CF₃

{CpRu(PPh3)2}2(μ-SH)(OTf)

[ruthenium(II)I(η5-C5H5)(P(C6H5)3)2]

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