(Z)-methyl 6-(1-methyl-2-methylene-1-cyclopropyl)-4-(phenylmethoxy)-2-hexenoate

Base Information

Chemical Name:(Z)-methyl 6-(1-methyl-2-methylene-1-cyclopropyl)-4-(phenylmethoxy)-2-hexenoate
CAS No.:133886-45-0
Molecular Formula:C₁₉H₂₄O₃
Molecular Weight:300.398
Hs Code.:

Synonyms:(Z)-methyl 6-(1-methyl-2-methylene-1-cyclopropyl)-4-(phenylmethoxy)-2-hexenoate

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Chemical Property of (Z)-methyl 6-(1-methyl-2-methylene-1-cyclopropyl)-4-(phenylmethoxy)-2-hexenoate

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Technology Process of (Z)-methyl 6-(1-methyl-2-methylene-1-cyclopropyl)-4-(phenylmethoxy)-2-hexenoate

There total 5 articles about (Z)-methyl 6-(1-methyl-2-methylene-1-cyclopropyl)-4-(phenylmethoxy)-2-hexenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 67-56-1
methanol

: (Z)-4-Benzyloxy-6-(1-methyl-2-methylene-cyclopropyl)-hex-2-enoic acid

: 133886-45-0
(Z)-methyl 6-(1-methyl-2-methylene-1-cyclopropyl)-4-(phenylmethoxy)-2-hexenoate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; for 2h; Ambient temperature;
DOI:10.1016/0040-4020(96)00160-3

Reference yield:

: (Z)-6-(1-methyl-2-methylene-1-cyclopropyl)-4-(phenylmethoxy)-2-hexenal

: 133886-45-0
(Z)-methyl 6-(1-methyl-2-methylene-1-cyclopropyl)-4-(phenylmethoxy)-2-hexenoate

Guidance literature:: Multi-step reaction with 2 steps

1: NaClO₂, potassium dihydrogen phosphate, 2-methyl-2-butene / 2-methyl-propan-2-ol; H₂O / 2 h

2: 80 percent / DMAP, DCC / CH₂Cl₂ / 2 h / Ambient temperature

With dmap; sodium chlorite; potassium dihydrogenphosphate; 2-methyl-but-2-ene; dicyclohexyl-carbodiimide; In dichloromethane; water; tert-butyl alcohol;
DOI:10.1016/0040-4020(96)00160-3

Reference yield:

: (Z)-6-(1-methyl-2-methylene-1-cyclopropyl)-4-(phenylmethoxy)-2-hexen-1-ol

: 133886-45-0
(Z)-methyl 6-(1-methyl-2-methylene-1-cyclopropyl)-4-(phenylmethoxy)-2-hexenoate

Guidance literature:: Multi-step reaction with 3 steps

1: 97 percent / MnO₂, O₂ / CH₂Cl₂ / 5 h

2: NaClO₂, potassium dihydrogen phosphate, 2-methyl-2-butene / 2-methyl-propan-2-ol; H₂O / 2 h

3: 80 percent / DMAP, DCC / CH₂Cl₂ / 2 h / Ambient temperature

With dmap; manganese(IV) oxide; sodium chlorite; potassium dihydrogenphosphate; 2-methyl-but-2-ene; oxygen; dicyclohexyl-carbodiimide; In dichloromethane; water; tert-butyl alcohol;
DOI:10.1016/0040-4020(96)00160-3