tert-Butyl-[(4Z,9Z)-(1R,6S,7R,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1R,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyloxy]-dimethyl-silane

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Chemical Name:tert-Butyl-[(4Z,9Z)-(1R,6S,7R,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1R,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyloxy]-dimethyl-silane
CAS No.:623926-77-2
Molecular Formula:C₅₁H₈₀O₇Si
Molecular Weight:833.277
Hs Code.:

tert-Butyl-[(4Z,9Z)-(1R,6S,7R,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1R,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyloxy]-dimethyl-silane

Synonyms:tert-Butyl-[(4Z,9Z)-(1R,6S,7R,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1R,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyloxy]-dimethyl-silane

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Chemical Property of tert-Butyl-[(4Z,9Z)-(1R,6S,7R,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1R,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyloxy]-dimethyl-silane

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Technology Process of tert-Butyl-[(4Z,9Z)-(1R,6S,7R,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1R,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyloxy]-dimethyl-silane

There total 18 articles about tert-Butyl-[(4Z,9Z)-(1R,6S,7R,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1R,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyloxy]-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 54911-85-2
4-tetrahydropyranyloxybutanal

: [(5Z,13Z)-(2R,3S,4S,9R,10R,11S,12S)-9-(tert-Butyl-dimethyl-silanyloxy)-3,11-bis-(4-methoxy-benzyloxy)-2,4,10,12-tetramethyl-hexadeca-5,13,15-trienyl]-triphenyl-phosphonium; iodide

: 623926-77-2
tert-Butyl-[(4Z,9Z)-(1R,6S,7R,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1R,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyloxy]-dimethyl-silane

Guidance literature:: [(5Z,13Z)-(2R,3S,4S,9R,10R,11S,12S)-9-(tert-Butyl-dimethyl-silanyloxy)-3,11-bis-(4-methoxy-benzyloxy)-2,4,10,12-tetramethyl-hexadeca-5,13,15-trienyl]-triphenyl-phosphonium; iodide; With sodium hexamethyldisilazane;

4-tetrahydropyranyloxybutanal;
DOI:10.1016/S0968-0896(03)00186-X

Reference yield:

: 106296-58-6
(2S,3S,4S)-(1-tert-butyldimethylsilanyloxy)-2,4-dimethylhex-5-en-3-ol

: 623926-77-2
tert-Butyl-[(4Z,9Z)-(1R,6S,7R,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1R,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyloxy]-dimethyl-silane

Guidance literature:: Multi-step reaction with 9 steps

1.1: 89 percent / NaH / tetrahydrofuran; dimethylformamide / 48 h / 20 °C

2.1: ozone

2.2: 85 percent / NaBH₄

3.1: 94 percent / I₂; PPh₃; imidazole / diethyl ether; benzene

4.1: 92 percent / benzene / 80 °C

5.1: NaHMDS / tetrahydrofuran

5.2: 61 percent / tetrahydrofuran / -78 - 20 °C

6.1: 89 percent / HF-pyridine; pyridine

7.1: I₂; PPh₃; imidazole

8.1: benzene

9.1: 61 percent / NaHDMS

With pyridine; 1H-imidazole; iodine; sodium hexamethyldisilazane; sodium hydride; pyridine hydrogenfluoride; ozone; triphenylphosphine; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; benzene; 5.2: Wittig reaction / 9.2: Wittig reaction;
DOI:10.1016/S0968-0896(03)00186-X

Reference yield:

: 184291-95-0
(2S,3S,4S)-1-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethyl hex-5-ene

: 623926-77-2
tert-Butyl-[(4Z,9Z)-(1R,6S,7R,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1R,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyloxy]-dimethyl-silane

Guidance literature:: Multi-step reaction with 8 steps

1.1: ozone

1.2: 85 percent / NaBH₄

2.1: 94 percent / I₂; PPh₃; imidazole / diethyl ether; benzene

3.1: 92 percent / benzene / 80 °C

4.1: NaHMDS / tetrahydrofuran

4.2: 61 percent / tetrahydrofuran / -78 - 20 °C

5.1: 89 percent / HF-pyridine; pyridine

6.1: I₂; PPh₃; imidazole

7.1: benzene

8.1: 61 percent / NaHDMS

With pyridine; 1H-imidazole; iodine; sodium hexamethyldisilazane; pyridine hydrogenfluoride; ozone; triphenylphosphine; In tetrahydrofuran; diethyl ether; benzene; 4.2: Wittig reaction / 8.2: Wittig reaction;
DOI:10.1016/S0968-0896(03)00186-X