[Ru(η5-pentamethylcyclopentadienyl)(1,3-bis(diphenylphosphino)propane)(CNCH2C6H5)]Br

Base Information

Chemical Name:[Ru(η5-pentamethylcyclopentadienyl)(1,3-bis(diphenylphosphino)propane)(CNCH2C6H5)]Br
CAS No.:819072-52-1
Molecular Formula:Br*C₄₅H₄₈NP₂Ru
Molecular Weight:845.804
Hs Code.:

Synonyms:[Ru(η5-pentamethylcyclopentadienyl)(1,3-bis(diphenylphosphino)propane)(CNCH2C6H5)]Br

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Ru(η5-pentamethylcyclopentadienyl)(1,3-bis(diphenylphosphino)propane)(CNCH2C6H5)]Br

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Technology Process of [Ru(η5-pentamethylcyclopentadienyl)(1,3-bis(diphenylphosphino)propane)(CNCH2C6H5)]Br

There total 1 articles about [Ru(η5-pentamethylcyclopentadienyl)(1,3-bis(diphenylphosphino)propane)(CNCH2C6H5)]Br which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 204455-59-4
[Ru(η5-pentamethylcyclopentadienyl)(1,3-bis(diphenylphosphino)propane)(CN)]

: 100-39-0
benzyl bromide

: 819072-52-1
[Ru(η5-pentamethylcyclopentadienyl)(1,3-bis(diphenylphosphino)propane)(CNCH2C6H5)]Br

Guidance literature:: In chloroform; (N2); using Schlenk techniques; addn. of BrCH2Ph to soln. of Ru(C5Me5)(dppp)(CN) in CHCl3; reflux for 6 h; cooling, concn., addn. to Et2O; pptn., filtration, washing with Et2O andn-hexane, recrystn. from CH2Cl2/n-hexane (1:10); elem. anal.;
DOI:10.1021/om049528t

Reference yield: 60.0%

: 819072-52-1
[Ru(η5-pentamethylcyclopentadienyl)(1,3-bis(diphenylphosphino)propane)(CNCH2C6H5)]Br

: 67-64-1
acetone

: 819072-55-4
[Ru(η5-pentamethylcyclopentadienyl)(1,3-bis(diphenylphosphino)propane)(C3HNO(Ph)Me2)]

Guidance literature:: With (n-Bu)4NOH; In acetone; (N2); using Schlenk techniques; addn. of (n-Bu)4NOH to soln. of (Ru(dppp)(C5Me5)(CNCH2Ph))Br in acetone; stirring for 10 min; removal of solvent under vac., extn. with n-hexane, drying nder vac., recrystn. from n-hexane; elem. anal.;
DOI:10.1021/om049528t

Reference yield: 38.0%

: 17084-13-8
potassium hexafluorophosphate

: 819072-52-1
[Ru(η5-pentamethylcyclopentadienyl)(1,3-bis(diphenylphosphino)propane)(CNCH2C6H5)]Br

: 67-64-1
acetone

: 819072-61-2
[Ru(η5-pentamethylcyclopentadienyl)(1,3-bis(diphenylphospino)propane)(CNCH(Ph)CMe2OH)][PF6]

Guidance literature:: With NaOMe; In acetone; (N2); using Schlenk techniques; stirring of soln. of (Ru(C5Me5)(dppp)(CNCH2Ph))Br, NaOMe and KPF6 in acetone at room temp. for 3 days; removal of solvent under reduced pressure, recrystn from CH2Cl2/diethyl ether (1:10); elem. anal.;
DOI:10.1021/om049528t