N,N'-DI(2-HYDROXYETHYL)-PERYLENE-TETRACARBONIC ACID, DIAMIDE

Base Information

• Chemical Name: N,N'-DI(2-HYDROXYETHYL)-PERYLENE-TETRACARBONIC ACID, DIAMIDE
• CAS No.: 26872-64-0
• Molecular Formula: C₂₈H₁₈N₂O₆
• Molecular Weight: 478.461
• Mol file: 26872-64-0.mol

Synonyms:3,4,9,10-Perylenetetracarboxylic3,4:9,10-diimide, N,N'-bis(2-hydroxyethyl)- (8CI);N,N'-Bis(2-hydroxyethyl)-3,4:9,10-perylenebis(dicarboximide);N,N'-Bis(2-hydroxyethyl)-3,4:9,10-perylenetetracarboxylic diimide;N,N'-Bis(2-hydroxyethyl)perylene-3,4,9,10-tetracarboxylic 3,4:9,10-diimide

Chemical Property of N,N'-DI(2-HYDROXYETHYL)-PERYLENE-TETRACARBONIC ACID, DIAMIDE

Chemical Property:

• Boiling Point: 811.3±55.0 °C(Predicted)
• PKA: 14.05±0.10(Predicted)
• PSA: 118.60000
• Density: 1.635±0.06 g/cm3(Predicted)
• LogP: 1.94760

Purity/Quality:

≥99.0% ^*data from raw suppliers

2,9-DI(2-HYDROXYETHYL)-ANTHRA[2,1,9-DEF:6,5,10-D'E'F']DIISOQUINOLINE-1,3,8,10-TETRONE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N,N'-DI(2-HYDROXYETHYL)-PERYLENE-TETRACARBONIC ACID, DIAMIDE

There total 3 articles about N,N'-DI(2-HYDROXYETHYL)-PERYLENE-TETRACARBONIC ACID, DIAMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

ethanolamine (141-43-5) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → 2,9-bis(2-hydroxyethyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone (26872-64-0)

Guidance literature:

In neat (no solvent); at 110 ℃; for 0.1h; Green chemistry;

DOI:10.1002/anie.201913625

Reference yield: 28.0%

2-(2-hydroxyethyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione (5450-40-8) → 2,9-bis(2-hydroxyethyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone (26872-64-0)

Guidance literature:

With 2,6-dichloro-benzonitrile; potassium tert-butylate; In diethylene glycol dimethyl ether; at 130 ℃;

DOI:10.1021/jo0010835

Reference yield:

→ 2,9-bis(2-hydroxyethyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone (26872-64-0)

Guidance literature:

Perylentetracarbonsaeure-dianhydrid, Ethanolamin;

upstream raw materials:

2-(2-hydroxyethyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione

ethanolamine

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride