tris(trifluorophosphine)bis(triphenylphosphine)ruthenium⁽⁰⁾

Base Information

• Chemical Name: tris(trifluorophosphine)bis(triphenylphosphine)ruthenium⁽⁰⁾
• CAS No.: 67840-34-0
• Molecular Formula: C₃₆H₃₀F₉P₅Ru
• Molecular Weight: 889.559
• Mol file: 67840-34-0.mol

Synonyms:tris(trifluorophosphine)bis(triphenylphosphine)ruthenium⁽⁰⁾

Chemical Property of tris(trifluorophosphine)bis(triphenylphosphine)ruthenium⁽⁰⁾

Chemical Property:

Purity/Quality:

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Technology Process of tris(trifluorophosphine)bis(triphenylphosphine)ruthenium⁽⁰⁾

There total 2 articles about tris(trifluorophosphine)bis(triphenylphosphine)ruthenium⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.6%

RuH(OAc)(PPh3)3 (311819-28-0,25087-75-6,55354-87-5) + trifluorophosphane (7783-55-3) → tris(trifluorophosphine)bis(triphenylphosphine)ruthenium(0) (67840-34-0)

Guidance literature:

In dichloromethane; byproducts: CH3COOH; a mixt. of Ru-complex, ligand and CH2Cl2 was sealed off in an ampoule and warmed from -196°C to room temp., the mixt. was shaken overnight; evapd., washed with hexane, crystd. from CH2Cl2/hexane; elem. anal.;

DOI:10.1016/S0022-328X(00)82941-1

Reference yield: 39.0%

[RuH(trifluorophosphine)2(triphenylphosphine)2]BF4 + tetraethylammonium chloride (56-34-8) → tris(trifluorophosphine)bis(triphenylphosphine)ruthenium(0) (67840-34-0) + cis-chlorohydridobis(trifluorophosphine)bis(triphenylphosphine)ruthenium(II) (68448-09-9)

Guidance literature:

In dichloromethane; excess Et4NCl to Ru-complex soln., stirring (sealed vessel, vac., 30 min); solvent removal, extn. (C6H6), evapn. to dryness, washing (hexane), recrystn. (CH2Cl2/hexane); elem. anal.;

DOI:10.1039/DT9780000889

Reference yield: 92.5%

tris(trifluorophosphine)bis(triphenylphosphine)ruthenium(0) (67840-34-0) → cis-dichlorobis(trifluorophosphine)bis(triphenylphosphine)ruthenium(II) (55744-57-5)

Guidance literature:

With HCl; In benzene; 2 equiv. HCl (sealed vessel, vac., 100°C, 12 h); solvent removal, recrystn. (CH2Cl2/hexane); elem. anal.;

DOI:10.1039/DT9780000889

upstream raw materials:

RuH(OAc)(PPh₃)3

trifluorophosphane

tetraethylammonium chloride

Downstream raw materials:

cis-dichlorobis(trifluorophosphine)bis(triphenylphosphine)ruthenium(II)

cis-chlorohydridobis(trifluorophosphine)bis(triphenylphosphine)ruthenium(II)