(O2)iron(1-methylimidazole)(α,α,α,α-5,10,15,20-tetrakis[o-pivalamidophenyl]porphyrinate)

Base Information

Chemical Name:(O2)iron(1-methylimidazole)(α,α,α,α-5,10,15,20-tetrakis[o-pivalamidophenyl]porphyrinate)
CAS No.:75559-87-4
Molecular Formula:C₆₈H₇₀FeN₁₀O₆
Molecular Weight:1179.21
Hs Code.:

Synonyms:(O2)iron(1-methylimidazole)(α,α,α,α-5,10,15,20-tetrakis[o-pivalamidophenyl]porphyrinate)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (O2)iron(1-methylimidazole)(α,α,α,α-5,10,15,20-tetrakis[o-pivalamidophenyl]porphyrinate)

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Technology Process of (O2)iron(1-methylimidazole)(α,α,α,α-5,10,15,20-tetrakis[o-pivalamidophenyl]porphyrinate)

There total 4 articles about (O2)iron(1-methylimidazole)(α,α,α,α-5,10,15,20-tetrakis[o-pivalamidophenyl]porphyrinate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75557-96-9
bis(N-methylimidazole)[(all-cis)-5,10,15,20-tetrakis-[2-(2,2-dimethylpropionamido)phenyl]porphyrinato^(2-)]-iron(II)

: 75559-87-4
(O2)iron(1-methylimidazole)(α,α,α,α-5,10,15,20-tetrakis[o-pivalamidophenyl]porphyrinate)

Guidance literature:: With oxygen; In ⁽²⁾H₈-toluene; to a soln. of Fe-complex in toluene-d8 O2 was added (1 atm) at 25°C; detected by NMR (1)H;
DOI:10.1021/ja00386a027

Reference yield:

: 616-47-7
1-methyl-1H-imidazole

: 105118-92-1,92078-42-7,87334-91-6,86107-94-0,87334-93-8,87334-92-7,104486-25-1
chloroiron(III) meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinate

: 55449-22-4,75559-87-4
(5,10,15,20-tetrakis(α,α,α,α-O-pivalamidophenyl)porphyrinato)iron(II)(1-methylimidazole)(O2)

Guidance literature:: With sodium dithionite; ethanol; oxygen; In water; toluene; H2O adding to a toluene soln. of the porphyrin, solid Na2S2O4 adding under Ar, stirring vigorously for 3 h at 25°C, toluene layer sepg.,drying over Na2SO4, a toluene soln. of the ligand then deoxygenated EtOH adding, Ar replacing to N2-O2 mixt.; monitored by UV spectra; Kinetics;
DOI:10.1021/ja00301a016

Reference yield:

: 616-47-7
1-methyl-1H-imidazole

: 52275-89-5,75557-96-9
{Fe(meso-5,10,15,20-tetrakis(o-pivalamidophenyl)porphyrinato)(1-methylimidazole)2}

: 55449-22-4,75559-87-4
(5,10,15,20-tetrakis(α,α,α,α-O-pivalamidophenyl)porphyrinato)iron(II)(1-methylimidazole)(O2)

Guidance literature:: With hydrogen; oxygen; In ethanol; toluene; an aliquot of the diluted toluene soln. of the porphyrin and Me-imidazole was mixed with EtOH under Ar, then Ar was replaced by flushing with amixt. of H2-O2 gas; identified by UV spectrum;
DOI:10.1021/ja00301a016