methyl 6-[bis-(tert-butoxycarbonyl)amino]-2-hydroxy-3-(2-hydroxymethylfuran-3-yl)benzoate

Base Information

Chemical Name:methyl 6-[bis-(tert-butoxycarbonyl)amino]-2-hydroxy-3-(2-hydroxymethylfuran-3-yl)benzoate
CAS No.:1356112-02-1
Molecular Formula:C₂₃H₂₉NO₉
Molecular Weight:463.485
Hs Code.:

Synonyms:methyl 6-[bis-(tert-butoxycarbonyl)amino]-2-hydroxy-3-(2-hydroxymethylfuran-3-yl)benzoate

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Chemical Property of methyl 6-[bis-(tert-butoxycarbonyl)amino]-2-hydroxy-3-(2-hydroxymethylfuran-3-yl)benzoate

Chemical Property:

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Technology Process of methyl 6-[bis-(tert-butoxycarbonyl)amino]-2-hydroxy-3-(2-hydroxymethylfuran-3-yl)benzoate

There total 6 articles about methyl 6-[bis-(tert-butoxycarbonyl)amino]-2-hydroxy-3-(2-hydroxymethylfuran-3-yl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1356112-04-3
methyl 6-[bis-(tert-butoxycarbonyl)amino]-3-(2-hydroxymethyl-furan-3-yl)-2-(4-methylbenzenesulfonyloxy)benzoate

: 1356112-02-1
methyl 6-[bis-(tert-butoxycarbonyl)amino]-2-hydroxy-3-(2-hydroxymethylfuran-3-yl)benzoate

Guidance literature:: With water; sodium hydroxide; In methanol; at 45 ℃; for 1.5h;

Reference yield:

: 1356112-23-6
methyl 6-amino-3-(2-formylfuran-3-yl)-2-hydroxybenzoate

: 1356112-02-1
methyl 6-[bis-(tert-butoxycarbonyl)amino]-2-hydroxy-3-(2-hydroxymethylfuran-3-yl)benzoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: dmap; triethylamine / dichloromethane / 1 h

1.2: 2 h

2.1: ethanol; sodium tetrahydroborate / 0.25 h

3.1: sodium hydroxide; water / methanol / 1.5 h / 45 °C

With dmap; sodium tetrahydroborate; ethanol; water; triethylamine; sodium hydroxide; In methanol; dichloromethane;

Reference yield:

: 681247-11-0
methyl 6-amino-3-bromo-2-hydroxybenzoate

: 1356112-02-1
methyl 6-[bis-(tert-butoxycarbonyl)amino]-2-hydroxy-3-(2-hydroxymethylfuran-3-yl)benzoate

Guidance literature:: Multi-step reaction with 4 steps

1.1: caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate / tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / 1,4-dioxane; water / 1 h / 65 °C / Inert atmosphere

2.1: dmap; triethylamine / dichloromethane / 1 h

2.2: 2 h

3.1: ethanol; sodium tetrahydroborate / 0.25 h

4.1: sodium hydroxide; water / methanol / 1.5 h / 45 °C

With dmap; sodium tetrahydroborate; ethanol; water; caesium carbonate; triethylamine; sodium hydroxide; tri tert-butylphosphoniumtetrafluoroborate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In 1,4-dioxane; methanol; dichloromethane; water;