2-O-pentylglycerol monoether

Base Information

• Chemical Name: 2-O-pentylglycerol monoether
• CAS No.: 100078-37-3
• Molecular Formula: C₈H₁₈O₃
• Molecular Weight: 162.229
• Mol file: 100078-37-3.mol

Synonyms:2-O-pentylglycerol monoether

Chemical Property of 2-O-pentylglycerol monoether

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 2-O-pentylglycerol monoether

There total 8 articles about 2-O-pentylglycerol monoether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

monocaprylin (19670-49-6,502-54-5) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) → 3-octyloxy-1,2-propanediol (10438-94-5) + 2-O-pentylglycerol monoether (100078-37-3)

Guidance literature:

With 5%-palladium/activated carbon; hydrogen; at 120 ℃; for 16h; under 37503.8 Torr; regioselective reaction; Autoclave;

DOI:10.1039/c3gc36907b

Reference yield:

pentanal (110-62-3) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) → pentan-1-ol (71-41-0) + 3-pentoxy-1,2-propanediol (98451-39-9,119066-34-1,119066-35-2,22636-32-4) + 1,3-dipentyl glycerol (62883-83-4) + 2-O-pentylglycerol monoether (100078-37-3) + 1,2-dipentyl glycerol (69805-55-6)

Guidance literature:

With hydrogen; palladium 10% on activated carbon; at 200 ℃; for 8h; under 51716.2 Torr; Product distribution / selectivity; Inert atmosphere;

Reference yield:

methyl octanate (111-11-5) → 3-octyloxy-1,2-propanediol (10438-94-5) + 2-O-pentylglycerol monoether (100078-37-3)

Guidance literature:

Multi-step reaction with 2 steps

1: / 16 h / 140 °C / Inert atmosphere

2: 5%-palladium/activated carbon; hydrogen / 16 h / 120 °C / 37503.8 Torr / Autoclave

With 5%-palladium/activated carbon; hydrogen;

DOI:10.1039/c3gc36907b

upstream raw materials:

pentanal

glycerol

valeric acid

monocaprylin

Refernces

• 1、 Sutter, Marc,Dayoub, Wissam,Metay, Estelle,Raoul, Yann,Lemaire, Marc. "1-O-Alkyl (di)glycerol ethers synthesis from methyl esters and triglycerides by two pathways: Catalytic reductive alkylation and transesterification/reduction". supporting information. p. 786 - 797. Retrieved 2013/04/24.
• 2、 -. "PROCESS FOR MAKING POLYOL ETHERS". Page/Page column 11-13. . Retrieved 2011/09/16.