Ethyl 3-<2-(2-bromophenyl)ethyl>-2-methyl-4-oxocyclohex-2-enecarboxylate

Base Information

• Chemical Name: Ethyl 3-<2-(2-bromophenyl)ethyl>-2-methyl-4-oxocyclohex-2-enecarboxylate
• CAS No.: 150270-93-2
• Molecular Formula: C₁₈H₂₁BrO₃
• Molecular Weight: 365.267
• Mol file: 150270-93-2.mol

Synonyms:Ethyl 3-<2-(2-bromophenyl)ethyl>-2-methyl-4-oxocyclohex-2-enecarboxylate

Chemical Property of Ethyl 3-<2-(2-bromophenyl)ethyl>-2-methyl-4-oxocyclohex-2-enecarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Ethyl 3-<2-(2-bromophenyl)ethyl>-2-methyl-4-oxocyclohex-2-enecarboxylate

There total 1 articles about Ethyl 3-<2-(2-bromophenyl)ethyl>-2-methyl-4-oxocyclohex-2-enecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

4-carbethoxy-3-methyl-2-cyclohexen-1-one (487-51-4) + 1-bromo-2-(2-bromoethyl)benzene (1074-15-3) → Ethyl 3-<2-(2-bromophenyl)ethyl>-2-methyl-4-oxocyclohex-2-enecarboxylate (150270-93-2)

Guidance literature:

With potassium tert-butylate; In tert-butyl alcohol;

DOI:10.1039/c39930000809

Reference yield: 88.0%

methyllithium (917-54-4) + Ethyl 3-<2-(2-bromophenyl)ethyl>-2-methyl-4-oxocyclohex-2-enecarboxylate (150270-93-2) → Ethyl 3-[2-(2-bromophenyl)ethyl]-2,2-dimethyl-4-oxocyclohexanecarboxylate (198631-35-5)

Guidance literature:

With copper(l) iodide; boron trifluoride diethyl etherate; In diethyl ether; 1.) -50 deg C, 5 min, 2.) -30 deg C, 75 min;

Reference yield: 79.0%

Ethyl 3-<2-(2-bromophenyl)ethyl>-2-methyl-4-oxocyclohex-2-enecarboxylate (150270-93-2) → 2-<2-(2-Bromophenyl)ethyl>-3-methylcyclohex-2-enone (150270-94-3)

Guidance literature:

With potassium hydroxide; In ethanol; for 14h; Heating;

upstream raw materials:

4-carbethoxy-3-methyl-2-cyclohexen-1-one

1-bromo-2-(2-bromoethyl)benzene

Downstream raw materials:

Ethyl 3-[2-(2-bromophenyl)ethyl]-2,2-dimethyl-4-oxocyclohexanecarboxylate

2-<2-(2-Bromophenyl)ethyl>-3-methylcyclohex-2-enone

3,3-dimethyl-1-methylene-2-phenethylcyclohexane

ethyl 3-(β-phenylethyl)-2,2-dimethyl-4-methylenecyclohexancarboxylate