(10-Phenylanthracen-9-yl)boronic acid

Base Information

• Chemical Name: (10-Phenylanthracen-9-yl)boronic acid
• CAS No.: 334658-75-2
• Molecular Formula: C₂₀H₁₅BO₂
• Molecular Weight: 298.149
• Hs Code.: 2931900090
• Mol file: 334658-75-2.mol

Synonyms:(10-Phenyl-9-anthryl)boronic acid;10-Phenyl-9-anthracene boronic acid;

Chemical Property of (10-Phenylanthracen-9-yl)boronic acid

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.727
• Boiling Point: 521.325 °C at 760 mmHg
• PKA: 8.59±0.30(Predicted)
• Flash Point: 269.088 °C
• PSA: 40.46000
• Density: 1.274 g/cm³
• LogP: 3.33980
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Sensitive.: Light Sensitive
• Solubility.: Soluble in methanol.

Purity/Quality:

99.5%MIN ^*data from raw suppliers

(10-Phenylanthracen-9-yl)boronicAcid ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: It is used as pharmaceutical intermediate and as OLED materials. suzuki reaction

Technology Process of (10-Phenylanthracen-9-yl)boronic acid

There total 11 articles about (10-Phenylanthracen-9-yl)boronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.3%

Trimethyl borate (121-43-7,63156-11-6) + 9-bromo-10-phenylanthracene (23674-20-6) + water (7732-18-5) → 10-phenylanthracene-9-boronic acid (334658-75-2)

Guidance literature:

9-bromo-10-phenylanthracene; With n-butyllithium; In tetrahydrofuran; hexane; at -70 ℃; for 2h; Inert atmosphere;

Trimethyl borate; In tetrahydrofuran; hexane; at 20 ℃; for 12h; Inert atmosphere;

water; With hydrogenchloride; In tetrahydrofuran; hexane; for 0.5h; Inert atmosphere;

Reference yield: 91.0%

Trimethyl borate (121-43-7,63156-11-6) + 9-bromo-10-phenylanthracene (23674-20-6) → 10-phenylanthracene-9-boronic acid (334658-75-2)

Guidance literature:

9-bromo-10-phenylanthracene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 2h;

Trimethyl borate; In tetrahydrofuran; at -78 - 20 ℃; for 12h;

Reference yield: 80.0%

→ 10-phenylanthracene-9-boronic acid (334658-75-2)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

In tetrahydrofuran; hexane; at 20 ℃; for 6h;

upstream raw materials:

Trimethyl borate

9-bromo-10-phenylanthracene

phenylboronic acid

9-Bromoanthracene

Downstream raw materials:

9-phenylanthracene

9-(4'-bromo-[1,1'-biphenyl]-4-yl)-10-phenylanthracene

Refernces

• 1、 -. "Asymmetric antracene derivatives having two phenyl groups and organic light-emitting diode including the same". Paragraph 0305; 0312-03113. . Retrieved 2021/05/11.
• 2、 -. "Anthracene derivatives and organic light emitting devices comprising the same". Page/Page column 62. . Retrieved 2019/09/02.