2,6-Naphthalenedicarbonyl dichloride

Base Information

• Chemical Name: 2,6-Naphthalenedicarbonyl dichloride
• CAS No.: 2351-36-2
• Molecular Formula: C12H6Cl2O2
• Molecular Weight: 253.084
• Hs Code.: 2917399090
• UNII: UX6ZJ93MGT
• DSSTox Substance ID: DTXSID80392930
• Nikkaji Number: J385.413B
• Wikidata: Q82191458
• Mol file: 2351-36-2.mol

Synonyms:2351-36-2;2,6-NAPHTHALENEDICARBONYL DICHLORIDE;naphthalene-2,6-dicarbonyl dichloride;Naphthalene-2,6-dicarbonyl Chloride;2,6-Naphthoyl dichloride;26Nadoc;2,6-Naphthalenedicarboxylic acid dichloride;UX6ZJ93MGT;2,6-Naphthaloyl dichloride;2,6-Naphthalenedicarbonyl chloride;2,6-Naphthalenedicarboxylic acid-dichloride;2351-36-2 Naphthalene-2,6-dicarbonyl dichloride;UNII-UX6ZJ93MGT;YSZC014;SCHEMBL727139;DTXSID80392930;2,6-Naphthalenedicarbonyldichloride;BCP30612;naphthalene-2,6-dicarboyl dichloride;AS-75799;2,6-naphthalene dicarboxylic acid chloride;2,6-naphthalene-dicarboxylic acid dichloride;naphthalene-2,6-dicarboxylic acid dichloride;E74983;A853057;2,6-Naphthalenedicarbonyl dichloride;Naphthaline-2,6-dicarbonic acid dichloranhydride

Chemical Property of 2,6-Naphthalenedicarbonyl dichloride

Chemical Property:

• Melting Point: 185-185.5 °C
• Boiling Point: 383.4 °C at 760 mmHg
• Flash Point: 206.9 °C
• PSA: 34.14000
• Density: 1.434 g/cm³
• LogP: 3.59780
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 251.9744848
• Heavy Atom Count: 16
• Complexity: 273

Purity/Quality:

98%Min ^*data from raw suppliers

Naphthalene-2,6-dicarbonyldichloride 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C=CC(=C2)C(=O)Cl)C=C1C(=O)Cl

Technology Process of 2,6-Naphthalenedicarbonyl dichloride

There total 5 articles about 2,6-Naphthalenedicarbonyl dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

2,6-Naphthalenedicarboxylic acid (1141-38-4) → 2,6-dichloroformyl naphthalene (2351-36-2)

Guidance literature:

With thionyl chloride; N-benzyl-N,N,N-triethylammonium chloride; In 1,2-dichloro-ethane; for 12h; Heating;

DOI:10.1055/s-1991-26487

Reference yield: 65.0%

2,6-Naphthalenedicarboxylic acid (1141-38-4) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → 2,6-dichloroformyl naphthalene (2351-36-2)

Guidance literature:

In trichlorophosphate;

Reference yield: 56.0%

2,6-naphthalenedicarboxylic acid dipotassium salt → 2,6-dichloroformyl naphthalene (2351-36-2)

Guidance literature:

With oxalyl dichloride; In toluene; for 3h; Heating;

upstream raw materials:

2,6-Naphthalenedicarboxylic acid

N,N-dimethyl-formamide

oxalyl dichloride

dimethyl 2,6-naphthalenedicarboxylate

Downstream raw materials:

N,N'-Dicyclohexyl-2,6-naphthalenedicarboxamide

C₃₆H₃₆N₄O₄

C₃₅H₄₁N₅O₆

C₂₃H₂₃N₃O₂

Refernces

• 1、 Zhu, Guang Yuan,Meng, Miao,Tan, Ying Ning,Xiao, Xuan,Liu, Chun Y.. "Electronic Coupling between Two Covalently Bonded Dimolybdenum Units Bridged by a Naphthalene Group". . p. 6315 - 6322. Retrieved 2016.
• 2、 Pradhan, Subhashis,John, Rohith P.. "Self-assembled Pd6L4 cage and Pd4L4 square using hydrazide based ligands: Synthesis, characterization and catalytic activity in Suzuki-Miyaura coupling reactions". . p. 12453 - 12460. Retrieved 2016/02/12.