C₅₄H₈₂O₁₁Si

Base Information

Chemical Name:C₅₄H₈₂O₁₁Si
CAS No.:1032880-29-7
Molecular Formula:C₅₄H₈₂O₁₁Si
Molecular Weight:935.324
Hs Code.:

C<sub>54</sub>H<sub>82</sub>O<sub>11</sub>Si

Synonyms:C₅₄H₈₂O₁₁Si

Suppliers and Price of C₅₄H₈₂O₁₁Si

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₅₄H₈₂O₁₁Si

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₅₄H₈₂O₁₁Si

There total 19 articles about C₅₄H₈₂O₁₁Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1032880-24-2
C₅₁H₇₈O₁₁Si

: 77-76-9
2,2-dimethoxy-propane

: 1032880-29-7
C₅₄H₈₂O₁₁Si

Guidance literature:: C₅₁H₇₈O₁₁Si; 2,2-dimethoxy-propane; With pyridinium p-toluenesulfonate; In acetone; for 1h;

Molecular sieve;
DOI:10.1021/ol8008057

Reference yield:

: 101331-92-4
4-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-L-threose

: 1032880-29-7
C₅₄H₈₂O₁₁Si

Guidance literature:: Multi-step reaction with 14 steps

1.1: (-)-B-methoxydiisopinocamphenylborane / diethyl ether / 1 h / 0 - 20 °C

1.2: 3 h / -78 °C

2.1: sodium hydride / tetrahydrofuran / 1 h / -10 - 20 °C

2.2: 12 h / 20 °C

3.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 5 h / 0 - 20 °C

3.2: 2 h / Reflux

4.1: dimethyl sulfoxide; triethylamine; sulfur trioxide pyridine complex / dichloromethane / 2 h / -10 °C

5.1: 2-methyl-but-2-ene; sodium dihydrogenphosphate; sodium chlorite / water; tert-butyl alcohol / 1 h / -10 - 20 °C

6.1: toluene-4-sulfonic acid / dichloromethane / 3 h / 0 - 20 °C

7.1: pyridine; dmap / dichloromethane / 20 °C

8.1: tetrahydrofuran / 1 h / -78 °C

8.2: 0.03 h / -78 °C / Molecular sieve

9.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / toluene / 8 h / 20 °C

10.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 1.5 h / 20 °C

11.1: dimethyl sulfoxide; triethylamine; sulfur trioxide pyridine complex / dichloromethane / 2 h / 0 °C

12.1: boron trifluoride diethyl etherate / dichloromethane / 1 h / -78 °C

13.1: tetramethylammonium triacetoxyborohydride; acetic acid / acetonitrile / 12 h / -30 °C

14.1: pyridinium p-toluenesulfonate / acetone / 1 h

With pyridine; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; dmap; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; (-)-B-methoxydiisopinocamphenylborane; boron trifluoride diethyl etherate; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; sodium hydride; toluene-4-sulfonic acid; acetic acid; dimethyl sulfoxide; triethylamine; 9-bora-bicyclo[3.3.1]nonane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; tetramethylammonium triacetoxyborohydride; In tetrahydrofuran; diethyl ether; dichloromethane; water; acetone; toluene; acetonitrile; tert-butyl alcohol; 12.1: |Mukaiyama Aldol Addition;
DOI:10.3987/COM-12-S(N)54

Reference yield:

: 1032879-81-4
C₂₇H₃₈O₄Si

: 1032880-29-7
C₅₄H₈₂O₁₁Si

Guidance literature:: Multi-step reaction with 12 steps

1.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 5 h / 0 - 20 °C

1.2: 2 h / Reflux

2.1: dimethyl sulfoxide; triethylamine; sulfur trioxide pyridine complex / dichloromethane / 2 h / -10 °C

3.1: 2-methyl-but-2-ene; sodium dihydrogenphosphate; sodium chlorite / water; tert-butyl alcohol / 1 h / -10 - 20 °C

4.1: toluene-4-sulfonic acid / dichloromethane / 3 h / 0 - 20 °C

5.1: pyridine; dmap / dichloromethane / 20 °C

6.1: tetrahydrofuran / 1 h / -78 °C

6.2: 0.03 h / -78 °C / Molecular sieve

7.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / toluene / 8 h / 20 °C

8.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 1.5 h / 20 °C

9.1: dimethyl sulfoxide; triethylamine; sulfur trioxide pyridine complex / dichloromethane / 2 h / 0 °C

10.1: boron trifluoride diethyl etherate / dichloromethane / 1 h / -78 °C

11.1: tetramethylammonium triacetoxyborohydride; acetic acid / acetonitrile / 12 h / -30 °C

12.1: pyridinium p-toluenesulfonate / acetone / 1 h

With pyridine; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; dmap; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; boron trifluoride diethyl etherate; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; toluene-4-sulfonic acid; acetic acid; dimethyl sulfoxide; triethylamine; 9-bora-bicyclo[3.3.1]nonane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; tetramethylammonium triacetoxyborohydride; In tetrahydrofuran; dichloromethane; water; acetone; toluene; acetonitrile; tert-butyl alcohol; 10.1: |Mukaiyama Aldol Addition;
DOI:10.3987/COM-12-S(N)54