[(P(C₆H₅)2(C₅H₄N))ClPt(H₂(C₂H₅)2N₂C₂S₂)]⁽¹⁺⁾*Cl^(1-)=[(P(C₆H₅)2(C₅H₄N))ClPt(H₂(C₂H₅)2N₂C₂S₂)]Cl

Base Information

• Chemical Name: [(P(C₆H₅)2(C₅H₄N))ClPt(H₂(C₂H₅)2N₂C₂S₂)]⁽¹⁺⁾*Cl^(1-)=[(P(C₆H₅)2(C₅H₄N))ClPt(H₂(C₂H₅)2N₂C₂S₂)]Cl
• CAS No.: 281225-74-9
• Molecular Formula: C₂₃H₂₆ClN₃PPtS₂*Cl
• Molecular Weight: 705.571

Synonyms:[(P(C₆H₅)2(C₅H₄N))ClPt(H₂(C₂H₅)2N₂C₂S₂)]⁽¹⁺⁾*Cl^(1-)=[(P(C₆H₅)2(C₅H₄N))ClPt(H₂(C₂H₅)2N₂C₂S₂)]Cl

Chemical Property of [(P(C₆H₅)2(C₅H₄N))ClPt(H₂(C₂H₅)2N₂C₂S₂)]⁽¹⁺⁾*Cl^(1-)=[(P(C₆H₅)2(C₅H₄N))ClPt(H₂(C₂H₅)2N₂C₂S₂)]Cl

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Technology Process of [(P(C₆H₅)2(C₅H₄N))ClPt(H₂(C₂H₅)2N₂C₂S₂)]⁽¹⁺⁾*Cl^(1-)=[(P(C₆H₅)2(C₅H₄N))ClPt(H₂(C₂H₅)2N₂C₂S₂)]Cl

There total 1 articles about [(P(C₆H₅)2(C₅H₄N))ClPt(H₂(C₂H₅)2N₂C₂S₂)]⁽¹⁺⁾*Cl^(1-)=[(P(C₆H₅)2(C₅H₄N))ClPt(H₂(C₂H₅)2N₂C₂S₂)]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichlorobis(dimethyl sulfoxide)platinum(II) + 2-(diphenylphosphino)pyridine (37943-90-1) + N,N'-diethyldithiooxamide (16475-50-6) → [(P(C6H5)2(C5H4N))ClPt(H2(C2H5)2N2C2S2)](1+)*Cl(1-)=[(P(C6H5)2(C5H4N))ClPt(H2(C2H5)2N2C2S2)]Cl (281225-74-9)

Guidance literature:

In chloroform; mixing of cis-(Pt(Me2SO)2Cl2) and the phosphine in CHCl3, addn. of stoich. amt. of dithioxamide, room temp.for 0.5 h; concd., petroleum ether added, ppt. was sepd. and air-dried; elem. anal.;

DOI:10.1021/om991008o

Reference yield: 90.0%

[(P(C6H5)2(C5H4N))ClPt(H2(C2H5)2N2C2S2)](1+)*Cl(1-)=[(P(C6H5)2(C5H4N))ClPt(H2(C2H5)2N2C2S2)]Cl (281225-74-9) → [(P(C6H5)2(C5H4N))ClPt(H(C2H5)2N2C2S2)]

Guidance literature:

With sodium bicarbonate; In chloroform; sodium bicarbonate added to (P(C6H5)2(C5H4N))ClPt(H2(C2H5)2N2C2S2)Cl, stirred for 30 min; sodium bicarbonate removed by filtration, filtrate concd., ppt. collected and dried in air;

DOI:10.1107/S0108270102006303

Reference yield:

[(P(C6H5)2(C5H4N))ClPt(H2(C2H5)2N2C2S2)](1+)*Cl(1-)=[(P(C6H5)2(C5H4N))ClPt(H2(C2H5)2N2C2S2)]Cl (281225-74-9) → (A,C)-[(η3-allyl)palladium(II)(μ-N,N'-(diethyldithioxbisamidato)-κ-N,N'-Pd-κ-S,S'-Pt)(2-(diphenylphosphino)pyridine)(chloro)platinum(II)] (281225-80-7)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium bicarbonate / chloroform

2: methanol; chloroform

With sodium bicarbonate; In methanol; chloroform;

DOI:10.1021/om991008o

upstream raw materials:

2-(diphenylphosphino)pyridine

N,N'-diethyldithiooxamide

Downstream raw materials:

(A,C)-[(η3-allyl)palladium(II)(μ-N,N'-(diethyldithioxbisamidato)-κ-N,N'-Pd-κ-S,S'-Pt)(2-(diphenylphosphino)pyridine)(chloro)platinum(II)]

(η3-allyl-2κ3-C)(chloro-1κCl)(μ-N,N'-diethyldithioxamidato-1:2κ4-S,S':N,N')[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate

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