2-benzylprop-2-en-1-yl acetate

Base Information

• Chemical Name: 2-benzylprop-2-en-1-yl acetate
• CAS No.: 944130-58-9
• Molecular Formula: C₁₂H₁₄O₂
• Molecular Weight: 190.242
• Mol file: 944130-58-9.mol

Synonyms:2-benzylprop-2-en-1-yl acetate

Chemical Property of 2-benzylprop-2-en-1-yl acetate

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of 2-benzylprop-2-en-1-yl acetate

There total 3 articles about 2-benzylprop-2-en-1-yl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

[bis(acetoxy)iodo]benzene (3240-34-4) + 3-benzylbut-3-enoic acid (90252-79-2) → 2-benzylprop-2-en-1-yl acetate (944130-58-9)

Guidance literature:

In acetic acid; 1,2-dichloro-ethane; at 95 ℃; for 20h; Inert atmosphere;

DOI:10.1021/ol5022433

Reference yield:

2-benzylallyl alcohol (30457-89-7) + acetic anhydride (108-24-7) → 2-benzylprop-2-en-1-yl acetate (944130-58-9)

Guidance literature:

DOI:10.1021/ol0706511

Reference yield:

methallyl acetate (820-71-3) + phenylboronic acid (98-80-6) → (Z)-3-phenyl-2-methyl-2-propen-1-ol-acetate + 2-benzylprop-2-en-1-yl acetate (944130-58-9) + (2E)-2-methyl-3-phenylallyl acetate (65693-16-5) + C12H14O2

Guidance literature:

With copper (II)-fluoride; potassium hydrogen difluoride; silver(I) acetate; palladium diacetate; In acetone; at 85 ℃; for 5h; optical yield given as %de; chemoselective reaction;

DOI:10.1021/ol9009865

upstream raw materials:

2-benzylallyl alcohol

acetic anhydride

methallyl acetate

phenylboronic acid

Downstream raw materials:

(S,E)-2-[3-(2-benzylallyloxy)pent-1-enyl]furan

Refernces

• 1、 Su, Yijin,Jiao, Ning. "Control of chemo-, regio-, and stereoselectivities in ligand-free Pd-catalyzed oxidative heck reactions of arylboronic acids or alkenylboronate with allyl esters". supporting information; experimental part. p. 2980 - 2983. Retrieved 2009/12/05.
• 2、 Wang, Kan,Bungard, Christopher J.,Nelson, Scott G.. "Stereoselective olefin isomerization leading to asymmetric quaternary carbon construction". . p. 2325 - 2328. Retrieved 2008/02/10.