(2R,3S)-2-(2-methyl-3-trimethylsilyl-E-prop-2-en-1-yl)-3-(p-methoxybenzyloxy)octanal

Base Information

Chemical Name:(2R,3S)-2-(2-methyl-3-trimethylsilyl-E-prop-2-en-1-yl)-3-(p-methoxybenzyloxy)octanal
CAS No.:327165-58-2
Molecular Formula:C₂₃H₃₈O₃Si
Molecular Weight:390.638
Hs Code.:

Synonyms:(2R,3S)-2-(2-methyl-3-trimethylsilyl-E-prop-2-en-1-yl)-3-(p-methoxybenzyloxy)octanal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3S)-2-(2-methyl-3-trimethylsilyl-E-prop-2-en-1-yl)-3-(p-methoxybenzyloxy)octanal

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Technology Process of (2R,3S)-2-(2-methyl-3-trimethylsilyl-E-prop-2-en-1-yl)-3-(p-methoxybenzyloxy)octanal

There total 13 articles about (2R,3S)-2-(2-methyl-3-trimethylsilyl-E-prop-2-en-1-yl)-3-(p-methoxybenzyloxy)octanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 327165-42-4
(1E,4R,5S)-4-hydroxymethyl-5-p-methoxybenzyloxy-2-methyl-1-trimethylsilyl-1-decene

: 327165-58-2
(2R,3S)-2-(2-methyl-3-trimethylsilyl-E-prop-2-en-1-yl)-3-(p-methoxybenzyloxy)octanal

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In dichloromethane; at -78 - 0 ℃;
DOI:10.1021/ja048493l

Reference yield:

: 2186-92-7
p-Anisaldehyde dimethyl acetal

: 327165-58-2
(2R,3S)-2-(2-methyl-3-trimethylsilyl-E-prop-2-en-1-yl)-3-(p-methoxybenzyloxy)octanal

Guidance literature:: Multi-step reaction with 3 steps

1: 434 mg / PPTS / CH₂Cl₂ / 3 h / 20 °C

2: 91 percent / DIBAL-H / toluene; hexane / 32 h / 20 °C

3: oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / -78 - 0 °C

With oxalyl dichloride; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; In hexane; dichloromethane; toluene; 3: Swern oxidation;
DOI:10.1021/ja048493l

Reference yield:

: (1E,4R)-5-hydroxy-2-methyl-4-hydroxymethyl-1-trimethylsilyl-1-decene

: 327165-58-2
(2R,3S)-2-(2-methyl-3-trimethylsilyl-E-prop-2-en-1-yl)-3-(p-methoxybenzyloxy)octanal

Guidance literature:: Multi-step reaction with 3 steps

1: 434 mg / PPTS / CH₂Cl₂ / 3 h / 20 °C

2: 91 percent / DIBAL-H / toluene; hexane / 32 h / 20 °C

3: oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / -78 - 0 °C

With oxalyl dichloride; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; In hexane; dichloromethane; toluene; 3: Swern oxidation;
DOI:10.1021/ja048493l