(1E,4R,5S)-4-hydroxymethyl-5-p-methoxybenzyloxy-2-methyl-1-trimethylsilyl-1-decene

Base Information

Chemical Name:(1E,4R,5S)-4-hydroxymethyl-5-p-methoxybenzyloxy-2-methyl-1-trimethylsilyl-1-decene
CAS No.:327165-42-4
Molecular Formula:C₂₃H₄₀O₃Si
Molecular Weight:392.654
Hs Code.:

Synonyms:(1E,4R,5S)-4-hydroxymethyl-5-p-methoxybenzyloxy-2-methyl-1-trimethylsilyl-1-decene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1E,4R,5S)-4-hydroxymethyl-5-p-methoxybenzyloxy-2-methyl-1-trimethylsilyl-1-decene

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Technology Process of (1E,4R,5S)-4-hydroxymethyl-5-p-methoxybenzyloxy-2-methyl-1-trimethylsilyl-1-decene

There total 12 articles about (1E,4R,5S)-4-hydroxymethyl-5-p-methoxybenzyloxy-2-methyl-1-trimethylsilyl-1-decene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 749900-34-3
(2R,4S,5S)-5-(2-methyl-3-trimethylsilyl-E-prop-2-en-1-yl)-2-(4-methoxyphenyl)-4-pentyl-1,3-dioxane

: 327165-42-4
(1E,4R,5S)-4-hydroxymethyl-5-p-methoxybenzyloxy-2-methyl-1-trimethylsilyl-1-decene

Guidance literature:: With diisobutylaluminium hydride; In hexane; toluene; at 20 ℃; for 32h;
DOI:10.1021/ja048493l

Reference yield: 91.0%

: 327165-57-1
{(E)-3-[(4S,5S)-2-(4-Methoxy-phenyl)-4-pentyl-[1,3]dioxan-5-yl]-2-methyl-propenyl}-trimethyl-silane

: 327165-42-4
(1E,4R,5S)-4-hydroxymethyl-5-p-methoxybenzyloxy-2-methyl-1-trimethylsilyl-1-decene

Guidance literature:: With diisobutylaluminium hydride; In hexane; toluene; at 23 ℃; for 32h;
DOI:10.1021/ol0069610

Reference yield:

: 2186-92-7
p-Anisaldehyde dimethyl acetal

: 327165-42-4
(1E,4R,5S)-4-hydroxymethyl-5-p-methoxybenzyloxy-2-methyl-1-trimethylsilyl-1-decene

Guidance literature:: Multi-step reaction with 2 steps

1: 434 mg / PPTS / CH₂Cl₂ / 3 h / 20 °C

2: 91 percent / DIBAL-H / toluene; hexane / 32 h / 20 °C

With pyridinium p-toluenesulfonate; diisobutylaluminium hydride; In hexane; dichloromethane; toluene;
DOI:10.1021/ja048493l