(rac)-2,8-dibromo-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine

Base Information

Chemical Name:(rac)-2,8-dibromo-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine
CAS No.:390357-38-7
Molecular Formula:C₁₇H₁₆Br₂N₂
Molecular Weight:408.135
Hs Code.:

Synonyms:(rac)-2,8-dibromo-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (rac)-2,8-dibromo-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine

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Technology Process of (rac)-2,8-dibromo-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine

There total 1 articles about (rac)-2,8-dibromo-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 106-49-0,12221-03-3
p-toluidine

: 583-75-5
4-Bromo-2-methylaniline

: 529-81-7
Troeger's base

: C₁₇H₁₇BrN₂

: 390357-38-7
(rac)-2,8-dibromo-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine

Guidance literature:: With trifluoroacetic acid; at 20 ℃; for 24h;
DOI:10.1002/mrc.4872

Reference yield: 91.0%

: 390357-38-7
(rac)-2,8-dibromo-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine

: 98-80-6
phenylboronic acid

: 4,10-dimethyl-2,8-diphenyl-6H,12H-5,11-methanodibenzo[b,f]diazocine

Guidance literature:: With potassium fluoride; bis(tri-t-butylphosphine)palladium⁽⁰⁾; In tetrahydrofuran; at 40 ℃; for 24h;
DOI:10.1055/s-2004-829117

Reference yield: 88.0%

: 540-37-4
p-aminoiodobenzene

: 390357-38-7
(rac)-2,8-dibromo-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine

: 2,8-bis(4-aminophenyl)-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f]diazocine

Guidance literature:: (rac)-2,8-dibromo-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.0833333h;

With Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 0.25h;

p-aminoiodobenzene; With cesium fluoride; bis(tri-t-butylphosphine)palladium⁽⁰⁾; In tetrahydrofuran; hexane; for 48h; Heating;
DOI:10.1055/s-2004-829117