13-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,4,7,10-tetraoxa-13-azacyclopentadecane

Base Information

Chemical Name:13-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,4,7,10-tetraoxa-13-azacyclopentadecane
CAS No.:1160928-61-9
Molecular Formula:C₂₂H₃₆BNO₆
Molecular Weight:421.342
Hs Code.:

Synonyms:13-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,4,7,10-tetraoxa-13-azacyclopentadecane

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Chemical Property of 13-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,4,7,10-tetraoxa-13-azacyclopentadecane

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Technology Process of 13-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,4,7,10-tetraoxa-13-azacyclopentadecane

There total 2 articles about 13-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,4,7,10-tetraoxa-13-azacyclopentadecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.6%

: 13-(4-iodophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane

: 73183-34-3
bis(pinacol)diborane

: 1160928-61-9
13-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,4,7,10-tetraoxa-13-azacyclopentadecane

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; potassium acetate; In dimethyl sulfoxide; at 80 ℃; for 12h; Inert atmosphere;
DOI:10.1021/ol900902z

Reference yield:

: 73183-34-3
bis(pinacol)diborane

: 169784-42-3
13-(4-bromophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane

: 1160928-61-9
13-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,4,7,10-tetraoxa-13-azacyclopentadecane

Guidance literature:: With C₄H₉Li; I₂; PdCl₂(P(C₆H₅)3)2); In not given; reaction with C4H9Li at -78 °C, then with I2; (BPin)2, PdCl2(P(C6H5)3)2 and KO2CCH3 added;
DOI:10.1002/ejic.201000673

Reference yield: 71.2%

: 1160928-61-9
13-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,4,7,10-tetraoxa-13-azacyclopentadecane

: ortho-nitropiperonal

: 1160928-58-4
[4-(1-aza-15-crown-5)phenyl]-(4,5-methylenedioxy-2-nitrophenyl)-methanol

Guidance literature:: 13-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,4,7,10-tetraoxa-13-azacyclopentadecane; ortho-nitropiperonal; With tri-1-napthylphosphine; potassium carbonate; palladium dichloride; In tetrahydrofuran; at 23 - 60 ℃; for 24.5h;

With water; In tetrahydrofuran; diethyl ether;
DOI:10.1021/ol900902z