3-(3-(tert-butyldimethylsilyloxy)propyl)-6,6-dimethyl-3-(prop-1-en-2-yl)cyclohex-1-enyl trifluoromethanesulfonate

Base Information

Chemical Name:3-(3-(tert-butyldimethylsilyloxy)propyl)-6,6-dimethyl-3-(prop-1-en-2-yl)cyclohex-1-enyl trifluoromethanesulfonate
CAS No.:1169876-16-7
Molecular Formula:C₂₁H₃₇F₃O₄SSi
Molecular Weight:470.669
Hs Code.:

Synonyms:3-(3-(tert-butyldimethylsilyloxy)propyl)-6,6-dimethyl-3-(prop-1-en-2-yl)cyclohex-1-enyl trifluoromethanesulfonate

Suppliers and Price of 3-(3-(tert-butyldimethylsilyloxy)propyl)-6,6-dimethyl-3-(prop-1-en-2-yl)cyclohex-1-enyl trifluoromethanesulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-(3-(tert-butyldimethylsilyloxy)propyl)-6,6-dimethyl-3-(prop-1-en-2-yl)cyclohex-1-enyl trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-(3-(tert-butyldimethylsilyloxy)propyl)-6,6-dimethyl-3-(prop-1-en-2-yl)cyclohex-1-enyl trifluoromethanesulfonate

There total 2 articles about 3-(3-(tert-butyldimethylsilyloxy)propyl)-6,6-dimethyl-3-(prop-1-en-2-yl)cyclohex-1-enyl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 5-(3-(tert-butyldimethylsilyloxy)propyl)-2,2-dimethyl-5-(prop-1-en-2-yl)cyclohexanone

: 145100-51-2
N-(5-chloropyridin-2-yl)-1,1,1-trifluoro-N-[(trifluoromethyl)sulphonyl]methanesulphonamide

: 1169876-16-7
3-(3-(tert-butyldimethylsilyloxy)propyl)-6,6-dimethyl-3-(prop-1-en-2-yl)cyclohex-1-enyl trifluoromethanesulfonate

Guidance literature:: 5-(3-(tert-butyldimethylsilyloxy)propyl)-2,2-dimethyl-5-(prop-1-en-2-yl)cyclohexanone; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 ℃; Inert atmosphere;

N-(5-chloropyridin-2-yl)-1,1,1-trifluoro-N-[(trifluoromethyl)sulphonyl]methanesulphonamide; In tetrahydrofuran; hexane; at -78 - 0 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2009.09.035

Reference yield: 64.0%

: 1071178-87-4
3-(3-(tert-butyldimethylsilanyloxy)propyl)-6,6-dimethylcyclohex-2-enone

: 13291-18-4
isopropenylmagnesium bromide

: 145100-51-2
N-(5-chloropyridin-2-yl)-1,1,1-trifluoro-N-[(trifluoromethyl)sulphonyl]methanesulphonamide

: 1169876-16-7
3-(3-(tert-butyldimethylsilyloxy)propyl)-6,6-dimethyl-3-(prop-1-en-2-yl)cyclohex-1-enyl trifluoromethanesulfonate

Guidance literature:: 3-(3-(tert-butyldimethylsilanyloxy)propyl)-6,6-dimethylcyclohex-2-enone; isopropenylmagnesium bromide; With copper(l) iodide;

N-(5-chloropyridin-2-yl)-1,1,1-trifluoro-N-[(trifluoromethyl)sulphonyl]methanesulphonamide; With lithium diisopropyl amide; at -45 - 20 ℃;
DOI:10.1016/j.tetlet.2009.02.025

Reference yield: 83.0%

: 201230-82-2
carbon monoxide

: 1169876-16-7
3-(3-(tert-butyldimethylsilyloxy)propyl)-6,6-dimethyl-3-(prop-1-en-2-yl)cyclohex-1-enyl trifluoromethanesulfonate

: 504-63-2
trimethyleneglycol

: 1169876-26-9
3-hydroxypropyl 3-(3-(tert-butyldimethylsilyloxy)propyl)-6,6-dimethyl-3-(prop-1-en-2-yl)cyclohex-1-enecarboxylate

Guidance literature:: With palladium diacetate; triethylamine; triphenylphosphine; In N,N-dimethyl-formamide; at 40 - 50 ℃;
DOI:10.1016/j.tetlet.2009.02.025