Tris (triphenylphosphine)Nickel(O)

Base Information

Chemical Name:Tris (triphenylphosphine)Nickel(O)
CAS No.:25136-46-3
Molecular Formula:C54H45 Ni P3
Molecular Weight:845.563
Hs Code.:
Mol file:25136-46-3.mol

Synonyms:Tris(triphenylphosphine)nickel;Tris(triphenylphosphine)nickel(0)

Suppliers and Price of Tris (triphenylphosphine)Nickel(O)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 14 raw suppliers

Chemical Property of Tris (triphenylphosphine)Nickel(O)

Chemical Property:

PSA：40.77000
LogP:10.33440

Purity/Quality:: 98%Min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Tris (triphenylphosphine)Nickel(O)

There total 14 articles about Tris (triphenylphosphine)Nickel(O) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 23777-40-4
bis(triphenylphosphine)ethylenenickel⁽⁰⁾

: 55091-64-0
1-methyl-1-phenyl-2-bromocyclopropane

: 25136-46-3
tris(triphenylphosphine)nickel⁽⁰⁾

: bromo(η3-1-methyl-1-phenylallyl)triphenylphosphinenickel

Guidance literature:: In benzene; addn. of the cyclopropane in benzene to the Ni compd. in benzene and keeping at 22°C for 24 h (Ar), addn. of ether, ppt. (allyl complex) is filtered off, washed (ether) and dried (vac.); concn., evapn. of the mother liquors and washings, treating with ether, filtn., washing with ether and drying (vac.) yields Ni(PPh3)3; elem. anal.;
DOI:10.1016/0022-328X(90)87131-V

Reference yield: 35.0%

: 1295-35-8
bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

: 754-05-2
ethenyltrimethylsilane

: 25136-46-3
tris(triphenylphosphine)nickel⁽⁰⁾

: 82631-87-6
π-(trimethylvinylsilane)bis(triphenylphosphine)nickel(0)

Guidance literature:: With triphenylphosphine; In benzene; (Ar); PPh3 (2 equiv) soln. added to complex and vinyltrimethylsilane mixt. in C6H6 at 22°C, stirred for 18 h; evapd., dissolved in ether, treated with pentane, ppt. filtered off, washed with pentane, dried (vac.); elem. anal.;
DOI:10.1016/S0022-328X(00)98719-9

Reference yield:

: 603-35-0
triphenylphosphine

: 83864-14-6
nickel dichloride

: 25136-46-3
tris(triphenylphosphine)nickel⁽⁰⁾

Guidance literature:: triphenylphosphine; nickel dichloride; In acetonitrile; for 1h; Reflux;

With zinc; In acetonitrile; at 20 ℃; Inert atmosphere;
DOI:10.1016/j.jallcom.2018.06.241