(triphenylphosphine)3(CO)nickelk

Base Information

Chemical Name:(triphenylphosphine)3(CO)nickelk
CAS No.:15376-83-7
Molecular Formula:C₅₅H₄₅NiOP₃
Molecular Weight:873.573
Hs Code.:

Synonyms:(triphenylphosphine)3(CO)nickelk

Suppliers and Price of (triphenylphosphine)3(CO)nickelk

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 3 raw suppliers

Chemical Property of (triphenylphosphine)3(CO)nickelk

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (triphenylphosphine)3(CO)nickelk

There total 22 articles about (triphenylphosphine)3(CO)nickelk which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1295-35-8
bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

: 104-57-4
benzyl formate

: 15376-83-7
(triphenylphosphine)3(CO)nickelk

: 100-52-7
benzaldehyde

: 100-51-6,185532-71-2
benzyl alcohol

Guidance literature:: With triphenylphosphine; In diethyl ether; byproducts: 1,3-cyclooctadiene, 1,4-cyclooctadiene, bicyclooctene-1; ester added to Schlenk tube contg. Ni(cod)2, PPh3, and Et2O at room temp., stirred at 65°C for 4 h; cooled down to -30°C; GLC anal.;
DOI:10.1246/bcsj.55.623

Reference yield: 90.0%

: 1295-35-8
bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

: 13098-94-7
Propansaeure-(4-methoxyphenyl)ester

: 15376-83-7
(triphenylphosphine)3(CO)nickelk

: 74-85-1
ethene

: 108-95-2,27073-41-2
phenol

Guidance literature:: With triphenylphosphine; In neat (no solvent); (N2 or Ar or vac.), EtCOOPh-OCH3 added to Ni(cod)2 and PPh3 (PPh3/Ni = 3), mixture stirred at 70°C for 8 h; GLC; Kinetics;
DOI:10.1021/ja00531a016

Reference yield: 80.0%

: 1295-35-8
bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

: 637-27-4,132899-52-6
phenyl propionate

: 15376-83-7
(triphenylphosphine)3(CO)nickelk

: 74-85-1
ethene

: 108-95-2,27073-41-2
phenol

Guidance literature:: With triphenylphosphine; In neat (no solvent); byproducts: diethyl ketone, 1,3-cyclooctadiene, 1,4-cyclooctadiene; further byproducts: 1,5-cyclooctadiene, bicyclooctene-1, bicyclooctene-2, (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and PPh3 (PPh3/Ni = 10), mixture stirred at 54°C for 21 h; gas chromy., volatile removed in vac., recrystd. from THF-hexane; Kinetics;
DOI:10.1021/ja00531a016