(μ-η2-3-methoxy-3-(3',4',5'-trimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl

Base Information

Chemical Name:(μ-η2-3-methoxy-3-(3',4',5'-trimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl
CAS No.:610802-83-0
Molecular Formula:C₁₉H₁₆Co₂O₁₀
Molecular Weight:522.316
Hs Code.:

Synonyms:(μ-η2-3-methoxy-3-(3',4',5'-trimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl

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Chemical Property of (μ-η2-3-methoxy-3-(3',4',5'-trimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl

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Technology Process of (μ-η2-3-methoxy-3-(3',4',5'-trimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl

There total 1 articles about (μ-η2-3-methoxy-3-(3',4',5'-trimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.4%

: 67-56-1
methanol

: 610802-74-9
[(CO)6Co₂(HCCCH(OH)C₆H₂(OCH₃)3)]

: 610802-83-0
(μ-η2-3-methoxy-3-(3',4',5'-trimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl

Guidance literature:: With HBF₄*(CH₃)2O; In methanol; diethyl ether; (N2); Schlenk technique; soln. of acid added dropwise over 5 min to soln. of Co complex in ether at -20°C; stirred for 1 h; ethereal layer removed; washed (ether, -20°C); ether added at -20°C; MeOH added; stirred (20°C, 0.5 h; dild. with H2O; org. layer washed (H2O); dried (Na2SO4); evapd. (vac.); elem. anal.;
DOI:10.1021/om900448j

Reference yield: 31.9%

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 610802-83-0
(μ-η2-3-methoxy-3-(3',4',5'-trimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl

: meso-μ-η2-[3,4-di(3',4',5'-trimethoxyphenyl)-1,5-hexadiyne]bis(dicobalthexacarbonyl)

: d,l-μ-η2-[3,4-di(3',4',5'-trimethoxyphenyl)-1,5-hexadiyne]bis(dicobalthexacarbonyl)

Guidance literature:: With trifluoromethylsulfonic anhydride; In 1,2-dichloro-ethane; (N2); Schlenk technique; anhydride added dropwise to Co complex/C2H4Cl2 (-20°C); stirred (-20°C, 10 min; 20°C, 10 min); re fluxed (83°C, 3 min); cooled (20°C); MeOH added; stirred (30 min); Co2(CO)8 added; stirred (2 h; dild. with H2O; extd. (ether); org. layer washed (H2O); dried (Na2SO4); evapd. (vac.); fractionally chromd. (silica gel, petroleum ether/ether, 1/2);
DOI:10.1021/om900448j