Technology Process of Ir2I2(μ2-SPh)2(COD)2*2CH2Cl2
There total 2 articles about Ir2I2(μ2-SPh)2(COD)2*2CH2Cl2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
I2;
In
tetrachloromethane; dichloromethane;
To a soln. of Ir2(SPH)2(COD)2 in dichloromethane was added a I2 soln. in CCl4. The soln. was stirred for 30 min.; The solvent was removed, and the residue was dissolved in CH2Cl2 and chromd. (silica gel in C6H14). Elution with CH2Cl2/hexane sepd. a deep-red band, which was collected and evapd. to dryness. Recrystn. (CH2Cl2/hexane). Elem.anal.;
- Guidance literature:
-
In
tetrahydrofuran;
Electrochem. Process; A soln. of Ir2(.mu2-I)2I2(COD)2 and of Bu4NPF6 in THF was placed in the cathodic compartment of the electrolytic cell. Working and auxiliary electrodes Pt disk and wire, respectively ;redn. 0,45 V vs. SCE. PhSSPh was added and stirred (15 min).; The soln. was evapd. to dryness, and the residue was extd. with toluene. The exts. were evapd. to dryness and purified by chromy. (silica gel in hexane). Elution with CH2Cl2 sepd. a deep red band, which was collected and evapd. to dryness.;
