(R)-10-benzyloxy-9-(tert-butyldimethylsilyloxy)-1-iododecane

Base Information

Chemical Name:(R)-10-benzyloxy-9-(tert-butyldimethylsilyloxy)-1-iododecane
CAS No.:681121-59-5
Molecular Formula:C₂₃H₄₁IO₂Si
Molecular Weight:504.567
Hs Code.:

Synonyms:(R)-10-benzyloxy-9-(tert-butyldimethylsilyloxy)-1-iododecane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R)-10-benzyloxy-9-(tert-butyldimethylsilyloxy)-1-iododecane

Chemical Property:

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Technology Process of (R)-10-benzyloxy-9-(tert-butyldimethylsilyloxy)-1-iododecane

There total 10 articles about (R)-10-benzyloxy-9-(tert-butyldimethylsilyloxy)-1-iododecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 681121-58-4
(R)-10-benzyloxy-9-(tert-butyldimethylsilyloxy)decan-1-ol

: 681121-59-5
(R)-10-benzyloxy-9-(tert-butyldimethylsilyloxy)-1-iododecane

Guidance literature:: With 1H-imidazole; iodine; triphenylphosphine; In tetrahydrofuran; at 20 ℃; for 0.25h;
DOI:10.1021/jo0303721

Reference yield:

: 13019-22-2
9-Decen-1-ol

: 681121-59-5
(R)-10-benzyloxy-9-(tert-butyldimethylsilyloxy)-1-iododecane

Guidance literature:: Multi-step reaction with 10 steps

1: 98 percent / NaH / dimethylformamide / 2.25 h / 0 - 20 °C

2: 98 percent / methanesulfonamide; AD-mix-β / H2O; 2-methyl-propan-2-ol / 6 h / 0 - 20 °C

3: 99 percent / PPTS / acetone / 0.83 h / 20 °C

4: 100 percent / H₂ / Pd(OH)2/C / ethyl acetate / 2.5 h / 20 °C

5: 99 percent / Et₃N; DMAP / CH₂Cl₂ / 2.5 h / 20 °C

6: 99 percent / aq. AcOH / 5.6 h / 20 °C

7: 64 percent / NaH / dimethylformamide / 0 - 20 °C

8: 97 percent / imidazole / dimethylformamide / 2.5 h / 20 °C

9: 97 percent / LiAlH₄ / tetrahydrofuran / 1.17 h / 0 - 20 °C

10: 98 percent / I₂; imidazole; PPh₃ / tetrahydrofuran / 0.25 h / 20 °C

With 1H-imidazole; dmap; lithium aluminium tetrahydride; methanesulfonamide; AD-mix-β; hydrogen; iodine; pyridinium p-toluenesulfonate; sodium hydride; acetic acid; triethylamine; triphenylphosphine; palladium dihydroxide; In tetrahydrofuran; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; acetone; tert-butyl alcohol;
DOI:10.1021/jo0303721

Reference yield:

: 100189-71-7
((dec-9-en-1-yloxy)methyl)benzene

: 681121-59-5
(R)-10-benzyloxy-9-(tert-butyldimethylsilyloxy)-1-iododecane

Guidance literature:: Multi-step reaction with 9 steps

1: 98 percent / methanesulfonamide; AD-mix-β / H2O; 2-methyl-propan-2-ol / 6 h / 0 - 20 °C

2: 99 percent / PPTS / acetone / 0.83 h / 20 °C

3: 100 percent / H₂ / Pd(OH)2/C / ethyl acetate / 2.5 h / 20 °C

4: 99 percent / Et₃N; DMAP / CH₂Cl₂ / 2.5 h / 20 °C

5: 99 percent / aq. AcOH / 5.6 h / 20 °C

6: 64 percent / NaH / dimethylformamide / 0 - 20 °C

7: 97 percent / imidazole / dimethylformamide / 2.5 h / 20 °C

8: 97 percent / LiAlH₄ / tetrahydrofuran / 1.17 h / 0 - 20 °C

9: 98 percent / I₂; imidazole; PPh₃ / tetrahydrofuran / 0.25 h / 20 °C

With 1H-imidazole; dmap; lithium aluminium tetrahydride; methanesulfonamide; AD-mix-β; hydrogen; iodine; pyridinium p-toluenesulfonate; sodium hydride; acetic acid; triethylamine; triphenylphosphine; palladium dihydroxide; In tetrahydrofuran; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; acetone; tert-butyl alcohol;
DOI:10.1021/jo0303721