tert-Butyl-((4R,5R)-5-[1,3]dithian-2-yl-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-diphenyl-silane

Base Information

Chemical Name:tert-Butyl-((4R,5R)-5-[1,3]dithian-2-yl-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-diphenyl-silane
CAS No.:218439-01-1
Molecular Formula:C₂₆H₃₆O₃S₂Si
Molecular Weight:488.788
Hs Code.:

Synonyms:tert-Butyl-((4R,5R)-5-[1,3]dithian-2-yl-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-diphenyl-silane

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Chemical Property of tert-Butyl-((4R,5R)-5-[1,3]dithian-2-yl-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-diphenyl-silane

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Technology Process of tert-Butyl-((4R,5R)-5-[1,3]dithian-2-yl-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-diphenyl-silane

There total 1 articles about tert-Butyl-((4R,5R)-5-[1,3]dithian-2-yl-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 77-76-9
2,2-dimethoxy-propane

: 218439-30-6
(1R,2R)-3-(tert-Butyl-diphenyl-silanyloxy)-1-[1,3]dithian-2-yl-propane-1,2-diol

: 218439-01-1
tert-Butyl-((4R,5R)-5-[1,3]dithian-2-yl-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-diphenyl-silane

Guidance literature:: With pyridinium p-toluenesulfonate; In dichloromethane; for 24h; Ambient temperature;
DOI:10.1246/bcsj.71.2433

Reference yield:

: 218439-01-1
tert-Butyl-((4R,5R)-5-[1,3]dithian-2-yl-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-diphenyl-silane

: 105368-84-1
4-O-[(tert-butyl)diphenylsilyl]-2,3-O-isopropylidene-D-erythrose

Guidance literature:: With mercury(II) perchlorate; calcium carbonate; In tetrahydrofuran; water; for 0.75h; Ambient temperature;
DOI:10.1246/bcsj.71.2433

Reference yield:

: 218439-01-1
tert-Butyl-((4R,5R)-5-[1,3]dithian-2-yl-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-diphenyl-silane

: 218439-09-9
(4S,5S)-5-((E)-5-Benzyloxymethoxy-pent-1-enyl)-2,2-dimethyl-[1,3]dioxolane-4-carbaldehyde

Guidance literature:: Multi-step reaction with 8 steps

1: Hg(ClO₄)2, CaCO₃ / tetrahydrofuran; H₂O / 0.75 h / Ambient temperature

2: tetrahydrofuran / 1 h / 0 - 5 °C

3: 68 percent / Hg(OAc)2 / Heating

4: 97 percent / decahydronaphthalene / 0.25 h / 200 °C

5: 99 percent / NaBH₄ / ethanol / 0.17 h / 0 °C

6: 228 mg / i-Pr₂NEt, NaI / tetrahydrofuran / 48 h / Ambient temperature

7: 114 mg / n-Bu₄NF / tetrahydrofuran / 1 h / Ambient temperature

8: 99 percent / Dess-Martin reagent, pyridine / CH₂Cl₂ / 0.08 h / Ambient temperature

With pyridine; sodium tetrahydroborate; mercury(II) perchlorate; mercury(II) diacetate; tetrabutyl ammonium fluoride; Dess-Martin periodane; N-ethyl-N,N-diisopropylamine; calcium carbonate; sodium iodide; In tetrahydrofuran; ethanol; dichloromethane; water; decalin;
DOI:10.1246/bcsj.71.2433