(1R,2R)-3-(tert-Butyl-diphenyl-silanyloxy)-1-[1,3]dithian-2-yl-propane-1,2-diol

Base Information

Chemical Name:(1R,2R)-3-(tert-Butyl-diphenyl-silanyloxy)-1-[1,3]dithian-2-yl-propane-1,2-diol
CAS No.:218439-30-6
Molecular Formula:C₂₃H₃₂O₃S₂Si
Molecular Weight:448.723
Hs Code.:

Synonyms:(1R,2R)-3-(tert-Butyl-diphenyl-silanyloxy)-1-[1,3]dithian-2-yl-propane-1,2-diol

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Chemical Property of (1R,2R)-3-(tert-Butyl-diphenyl-silanyloxy)-1-[1,3]dithian-2-yl-propane-1,2-diol

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Technology Process of (1R,2R)-3-(tert-Butyl-diphenyl-silanyloxy)-1-[1,3]dithian-2-yl-propane-1,2-diol

There total 1 articles about (1R,2R)-3-(tert-Butyl-diphenyl-silanyloxy)-1-[1,3]dithian-2-yl-propane-1,2-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 218439-29-3
D-erythrose propane-1,3-diyl dithioacetal

: 58479-61-1
tert-butylchlorodiphenylsilane

: 218439-30-6
(1R,2R)-3-(tert-Butyl-diphenyl-silanyloxy)-1-[1,3]dithian-2-yl-propane-1,2-diol

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; for 1h; Ambient temperature;
DOI:10.1246/bcsj.71.2433

Reference yield: 97.0%

: 77-76-9
2,2-dimethoxy-propane

: 218439-30-6
(1R,2R)-3-(tert-Butyl-diphenyl-silanyloxy)-1-[1,3]dithian-2-yl-propane-1,2-diol

: 218439-01-1
tert-Butyl-((4R,5R)-5-[1,3]dithian-2-yl-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-diphenyl-silane

Guidance literature:: With pyridinium p-toluenesulfonate; In dichloromethane; for 24h; Ambient temperature;
DOI:10.1246/bcsj.71.2433

Reference yield:

: 218439-30-6
(1R,2R)-3-(tert-Butyl-diphenyl-silanyloxy)-1-[1,3]dithian-2-yl-propane-1,2-diol

: 218439-07-7
(E)-5-[(4S,5R)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-pent-4-en-1-ol

Guidance literature:: Multi-step reaction with 6 steps

1: 97 percent / PPTS / CH₂Cl₂ / 24 h / Ambient temperature

2: Hg(ClO₄)2, CaCO₃ / tetrahydrofuran; H₂O / 0.75 h / Ambient temperature

3: tetrahydrofuran / 1 h / 0 - 5 °C

4: 68 percent / Hg(OAc)2 / Heating

5: 97 percent / decahydronaphthalene / 0.25 h / 200 °C

6: 99 percent / NaBH₄ / ethanol / 0.17 h / 0 °C

With sodium tetrahydroborate; mercury(II) perchlorate; mercury(II) diacetate; pyridinium p-toluenesulfonate; calcium carbonate; In tetrahydrofuran; ethanol; dichloromethane; water; decalin;
DOI:10.1246/bcsj.71.2433