Ni(CH₃)(OC₆H₅)(P(C₂H₅)3)2

Base Information

• Chemical Name: Ni(CH₃)(OC₆H₅)(P(C₂H₅)3)2
• CAS No.: 95910-33-1
• Molecular Formula: C₁₉H₃₈NiOP₂
• Molecular Weight: 403.148
• Mol file: 95910-33-1.mol

Synonyms:Ni(CH₃)(OC₆H₅)(P(C₂H₅)3)2

Chemical Property of Ni(CH₃)(OC₆H₅)(P(C₂H₅)3)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Ni(CH₃)(OC₆H₅)(P(C₂H₅)3)2

There total 4 articles about Ni(CH₃)(OC₆H₅)(P(C₂H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

NiMe2(PEt3)2 + Phenyl acetate (122-79-2,34474-31-2) → NiCH3(OC6H5)(P(C2H5)3)2 (95910-33-1,72918-81-1) + methane (34557-54-5,27936-85-2) + ethane (74-84-0) + acetone (67-64-1)

Guidance literature:

In diethyl ether; AcOPh added to ethereal soln. of Ni complex; pptd. by addn. of hexane; GLC anal.;

DOI:10.1246/bcsj.54.2010

Reference yield:

NiMe2(PEt3)2 + phenyl propionate (637-27-4,132899-52-6) → NiCH3(OC6H5)(P(C2H5)3)2 (95910-33-1,72918-81-1)

Guidance literature:

In neat (no solvent); byproducts: C2H5COCH3, acetone; (N2 or Ar or vac.), Ni-complex reacted at room temp. with C2H5COOC6H5;

DOI:10.1021/ja00531a016

Reference yield:

NiMe2(PEt3)2 → Ni(CH3)(OC6H5)(P(C2H5)3)2 (95910-33-1)

Guidance literature:

With phenol; In diethyl ether; byproducts: CH4; N2 or Ar), educts added at room temp.; after 2 h concentrated and chilled to -20°C, recrystd.;

DOI:10.1021/om00125a033

upstream raw materials:

phenyl propionate

Phenyl acetate

Downstream raw materials:

(CO)2Ni(P(C₂H₅)3)2

Phenyl acetate