4-(1-(trans-5-((tert-butyldimethylsilyl)oxy)-6-butylcyclohexenyl))butanol

Base Information

Chemical Name:4-(1-(trans-5-((tert-butyldimethylsilyl)oxy)-6-butylcyclohexenyl))butanol
CAS No.:120883-57-0
Molecular Formula:C₂₀H₄₀O₂Si
Molecular Weight:340.622
Hs Code.:

Synonyms:4-(1-(trans-5-((tert-butyldimethylsilyl)oxy)-6-butylcyclohexenyl))butanol

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Chemical Property of 4-(1-(trans-5-((tert-butyldimethylsilyl)oxy)-6-butylcyclohexenyl))butanol

Chemical Property:

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Technology Process of 4-(1-(trans-5-((tert-butyldimethylsilyl)oxy)-6-butylcyclohexenyl))butanol

There total 12 articles about 4-(1-(trans-5-((tert-butyldimethylsilyl)oxy)-6-butylcyclohexenyl))butanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 120883-56-9
trans-3-butyl-4-((tert-butyldimethylsilyl)oxy)-2-(4-(phenylmethoxy)butyl)cyclohexene

: 120883-57-0
4-(1-(trans-5-((tert-butyldimethylsilyl)oxy)-6-butylcyclohexenyl))butanol

Guidance literature:: With ammonia; sodium; In diethyl ether; at -78 ℃; for 1h;
DOI:10.1021/jo00275a023

Reference yield:

: 120883-61-6
trans-2-butyl-3-hydroxy-1-cyclohexanone

: 120883-57-0
4-(1-(trans-5-((tert-butyldimethylsilyl)oxy)-6-butylcyclohexenyl))butanol

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / imidazole / dimethylformamide / 3 h / Ambient temperature

2: 1.) LDA / 1.) THF, -78 deg C, 1 h, 2.) 12 h

3: 1.) copper(I) iodide / 1.) THF, -78 deg C, 30 min, 2.) -20 deg C, 12 h

4: 98 percent / ammonia, sodium / diethyl ether / 1 h / -78 °C

With 1H-imidazole; copper(l) iodide; ammonia; sodium; lithium diisopropyl amide; In diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jo00275a023

Reference yield:

: 120883-52-5
(4-Cyclohexa-1,5-dienyl-butoxymethyl)-benzene

: 120883-57-0
4-(1-(trans-5-((tert-butyldimethylsilyl)oxy)-6-butylcyclohexenyl))butanol

Guidance literature:: Multi-step reaction with 5 steps

1: 72 percent / LiCl, LiOAc*2H₂O, Pd(OAc)2, p-benzoquinone / acetone / 8 h

2: 89 percent / CuCN / diethyl ether / 4 h / 0 °C

3: 98 percent / 5percent aq. MeOH, K₂CO₃ / 24 h / Ambient temperature

4: 92 percent / imidazole / dimethylformamide / 3 h / 0 - 20 °C

5: 98 percent / ammonia, sodium / diethyl ether / 1 h / -78 °C

With 1H-imidazole; methanol; palladium diacetate; lithium acetate; ammonia; sodium; potassium carbonate; p-benzoquinone; lithium chloride; In diethyl ether; N,N-dimethyl-formamide; acetone;
DOI:10.1021/jo00275a023