1,4,7,10,13-Pentaoxacyclopentadecane-2-methanamine

Base Information

Chemical Name:1,4,7,10,13-Pentaoxacyclopentadecane-2-methanamine
CAS No.:83585-56-2
Molecular Formula:C11H23 N O5
Molecular Weight:249.307
Hs Code.:29329990
European Community (EC) Number:625-353-3
DSSTox Substance ID:DTXSID90409740
Nikkaji Number:J593.332C
Mol file:83585-56-2.mol

Synonyms:83585-56-2;1,4,7,10,13-Pentaoxacyclopentadecane-2-methanamine;2-Aminomethyl-15-crown-5;1,4,7,10,13-pentaoxacyclopentadec-2-ylmethanamine;(1,4,7,10,13-Pentaoxacyclopentadecan-2-yl)methanamine;SCHEMBL1246378;DTXSID90409740;2-Aminomethyl-15-crown-5, 95%;AKOS015894988;HY-W127831;AS-82221;Methyl-(4-methylfurazan-3-ylmethyl)amine;CS-0186001;FT-0750577;D96018

Suppliers and Price of 1,4,7,10,13-Pentaoxacyclopentadecane-2-methanamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2-Aminomethyl-15-crown-5
500mg
$ 210.00

TRC
2-Aminomethyl-15-crown-5
250mg
$ 130.00

Sigma-Aldrich
2-Aminomethyl-15-crown-5 95%
1g
$ 539.00

Sigma-Aldrich
2-Aminomethyl-15-crown-5 95%
250mg
$ 192.00

American Custom Chemicals Corporation
2-AMINOMETHYL-15-CROWN-5 PURUM 95.00%
1G
$ 1095.72

American Custom Chemicals Corporation
2-AMINOMETHYL-15-CROWN-5 PURUM 95.00%
250MG
$ 697.94

Total 20 raw suppliers

Chemical Property of 1,4,7,10,13-Pentaoxacyclopentadecane-2-methanamine

Chemical Property:

Vapor Pressure:2.83E-06mmHg at 25°C
Refractive Index:n20/D 1.48(lit.)
Boiling Point:115 °C0.08 mm Hg(lit.)
Flash Point:>230 °F
PSA：72.17000
Density:1.134 g/mL at 25 °C(lit.)
LogP:0.11060
XLogP3:-1.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:1
Exact Mass:249.15762283
Heavy Atom Count:17
Complexity:170

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Aminomethyl-15-crown-5 ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1COCCOCC(OCCOCCO1)CN
Uses 2-Aminomethyl-15-crown-5 is a crown ether with potential use for biochemical research.

Technology Process of 1,4,7,10,13-Pentaoxacyclopentadecane-2-methanamine

There total 7 articles about 1,4,7,10,13-Pentaoxacyclopentadecane-2-methanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 114012-79-2
1-amino-3-(2-hydroxy-ethoxy)-propan-2-ol

: 19249-03-7
triethylene glycol di-(p-toluenesulfonate)

: 83585-56-2
2-aminomethyl-15-crown-5

Guidance literature:: With sodium t-butanolate; In 1,4-dioxane; tert-butyl alcohol; at 40 ℃; for 2.5h;
DOI:10.1021/jo00147a025

Reference yield: 41.0%

: 83585-69-7
2-[1-Aminomethyl-2-(2-hydroxy-ethoxy)-ethoxy]-ethanol

: 7460-82-4
diethylene glycol ditosylate

: 83585-56-2
2-aminomethyl-15-crown-5

Guidance literature:: With sodium t-butanolate;
DOI:10.1021/jo00147a025

Reference yield:

: 18371-74-9
1-chloro-3-(2-hydroxyethoxy)-2-propanol

: 83585-56-2
2-aminomethyl-15-crown-5

Guidance literature:: Multi-step reaction with 2 steps

1: 53 percent / 26percent aq. NH₃, K₂CO₃ / 55 h / Ambient temperature

2: 53 percent / tert-BuONa / dioxane; 2-methyl-propan-2-ol / 2.5 h / 40 °C

With ammonium hydroxide; potassium carbonate; sodium t-butanolate; In 1,4-dioxane; tert-butyl alcohol;
DOI:10.1021/jo00147a025