[Ni(C₅H₅)(Sb(C₆H₅)2CH₂Sb(C₆H₅)2)2]⁽¹⁺⁾*BF₄^(1-)=[Ni(C₅H₅)(Sb(C₆H₅)2CH₂Sb(C₆H₅)2)2]BF₄

Base Information

• Chemical Name: [Ni(C₅H₅)(Sb(C₆H₅)2CH₂Sb(C₆H₅)2)2]⁽¹⁺⁾*BF₄^(1-)=[Ni(C₅H₅)(Sb(C₆H₅)2CH₂Sb(C₆H₅)2)2]BF₄
• CAS No.: 85836-38-0
• Molecular Formula: BF₄*C₅₅H₄₉NiSb₄
• Molecular Weight: 1342.49
• Mol file: 85836-38-0.mol

Synonyms:[Ni(C₅H₅)(Sb(C₆H₅)2CH₂Sb(C₆H₅)2)2]⁽¹⁺⁾*BF₄^(1-)=[Ni(C₅H₅)(Sb(C₆H₅)2CH₂Sb(C₆H₅)2)2]BF₄

Chemical Property of [Ni(C₅H₅)(Sb(C₆H₅)2CH₂Sb(C₆H₅)2)2]⁽¹⁺⁾*BF₄^(1-)=[Ni(C₅H₅)(Sb(C₆H₅)2CH₂Sb(C₆H₅)2)2]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ni(C₅H₅)(Sb(C₆H₅)2CH₂Sb(C₆H₅)2)2]⁽¹⁺⁾*BF₄^(1-)=[Ni(C₅H₅)(Sb(C₆H₅)2CH₂Sb(C₆H₅)2)2]BF₄

There total 1 articles about [Ni(C₅H₅)(Sb(C₆H₅)2CH₂Sb(C₆H₅)2)2]⁽¹⁺⁾*BF₄^(1-)=[Ni(C₅H₅)(Sb(C₆H₅)2CH₂Sb(C₆H₅)2)2]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

[Ni(C5H5)(Sb(C6H5)3)2](1+)*BF4(1-)=[Ni(C5H5)(Sb(C6H5)3)2]BF4 (85836-36-8) + bis(diphenylstibino)methane (30224-53-4) → [Ni(C5H5)(Sb(C6H5)2CH2Sb(C6H5)2)2](1+)*BF4(1-)=[Ni(C5H5)(Sb(C6H5)2CH2Sb(C6H5)2)2]BF4 (85836-38-0) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8)

Guidance literature:

In chloroform; under Ar, Ni complex in CHCl3 mixed at 0°C with stibane ligand (molar ratio 1:2), stirred for 10 min; filtered, to filtrate added ether, solid washed with ether, dried in vac., elem. anal.;

DOI:10.1016/S0022-328X(00)98585-1

Reference yield:

[Ni(C5H5)(Sb(C6H5)2CH2Sb(C6H5)2)2](1+)*BF4(1-)=[Ni(C5H5)(Sb(C6H5)2CH2Sb(C6H5)2)2]BF4 (85836-38-0) + lithium iodide (10377-51-2) → lithium tetrafluoroborate + [Ni(C5H5)(Sb(C6H5)2CH2Sb(C6H5)2)I] (85836-39-1)

Guidance literature:

In diethyl ether; LiI added to ether soln. of Ni complex (molar ratio 1:1);

DOI:10.1016/S0022-328X(00)98585-1

upstream raw materials:

[Ni(C₅H₅)(Sb(C₆H₅)3)2]⁽¹⁺⁾*BF₄^(1-)=[Ni(C₅H₅)(Sb(C₆H₅)3)2]BF₄

bis(diphenylstibino)methane

Downstream raw materials:

[Ni(C₅H₅)(Sb(C₆H₅)2CH₂Sb(C₆H₅)2)I]