Lithium iodide

Base Information

• Chemical Name: Lithium iodide
• CAS No.: 10377-51-2
• Deprecated CAS: 59216-97-6
• Molecular Formula: ILi
• Molecular Weight: 133.904
• Hs Code.: 2827600000
• European Community (EC) Number: 233-822-5,244-572-1,249-952-0
• UNII: S6K2XET783
• DSSTox Substance ID: DTXSID30908580
• Nikkaji Number: J43.854E
• Wikipedia: Lithium iodide
• Wikidata: Q79566
• Mol file: 10377-51-2.mol

Synonyms:Lithiumiodide (8CI);Lithium monoiodide;Lithium iodide (LiI);

Chemical Property of Lithium iodide

Chemical Property:

• Appearance/Colour: White to off-white crystalline powder
• Melting Point: 446 °C(lit.)
• Refractive Index: 1.955
• Boiling Point: 1171 °C
• Flash Point: 1170-1190 °C
• PSA: 0.00000
• Density: 3.49 g/mL at 25 °C(lit.)
• LogP: -2.99600
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 133.92048
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Safety Statements: S24/25:Avoid contact with skin and eyes.

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: [Li+].[I-]

Technology Process of Lithium iodide

There total 56 articles about Lithium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.8%

sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) + lithium chloride → lithium iodide (10377-51-2)

Guidance literature:

In acetone; at 60 ℃; for 1h;

Reference yield: 71.0%

gallium(III) iodide (13450-91-4) + lithium(2,6-diphenylphenyl) → ((C6H5)2C6H3)2GaI + lithium iodide (10377-51-2)

Guidance literature:

In diethyl ether; N2-atmosphere; stirring (-78°C, 3 h, room temp., 48 h), filteringLiI off; crystn. (-25°C, 1 week); elem. anal.;

DOI:10.1021/om980753i

Reference yield:

lithium (trifluoro methyl) iodo aluminate → aluminum trihydroxide + aluminum(III) fluoride (7784-18-1) + methane (34557-54-5,27936-85-2) + hydrogen (1333-74-0) + lithium iodide (10377-51-2)

Guidance literature:

With water; In water; decomposition with water;;

DOI:10.1021/ja01584a044

upstream raw materials:

iodine

lithium

lithium carbonate

lithium aluminium tetrahydride

Downstream raw materials:

triiodide^(1-)

sulfur

dicarbonylcyclopentadienyliodoiron(II)

tris(triphenylphosphine)rhodium(I) iodide

Refernces

• 1、 King,Partington. "-". . . Retrieved 1927.
• 2、 Crittendon, R. Chad,Beck, Brent C.,Su, Jianrui,Li, Xiao-Wang,Robinson, Gregory H.. "2,6-Diphenylphenyl-Based Organometallic Compounds of Gallium". . p. 156 - 160. Retrieved 1999.
• 3、 Davey. "". . p. 143 - 143. Retrieved 1923.
• 4、 Sofronov,Voloshko,Shishkin,Kudin. "Dehydration of lithium iodide crystal hydrate in vacuum". . p. 1675 - 1678. Retrieved 2007.
• 5、 Ljalikov, K.,Terenin, A.. "". . p. 107 - 107. Retrieved 1926.
• 6、 Rangasamy, Ezhiylmurugan,Liu, Zengcai,Gobet, Mallory,Pilar, Kartik,Sahu, Gayatri,Zhou, Wei,Wu, Hui,Greenbaum, Steve,Liang, Chengdu. "An iodide-based Li7P2S8I superionic conductor". . p. 1384 - 1387. Retrieved 2015.