cyclohexylimidovanadium(V)-trichloride

Base Information

• Chemical Name: cyclohexylimidovanadium(V)-trichloride
• CAS No.: 256385-95-2
• Molecular Formula: C₆H₁₁Cl₃NV
• Molecular Weight: 254.461
• Mol file: 256385-95-2.mol

Synonyms:cyclohexylimidovanadium(V)-trichloride

Chemical Property of cyclohexylimidovanadium(V)-trichloride

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of cyclohexylimidovanadium(V)-trichloride

There total 2 articles about cyclohexylimidovanadium(V)-trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

vanadium(V) oxychloride (7727-18-6) + Cyclohexyl isocyanate (3173-53-3) → cyclohexylimidovanadium(V)-trichloride (256385-95-2)

Guidance literature:

In octane; byproducts: CO2; (N2) to VOCl3 in n-octane cyclohexyl isocyanate was added, heated at 125°C overnight; react. mixt. was cooled, filtered through Celite and evapd., residue wasdissolved in hot n-hexane and cooled to -30°C; elem. anal.;

DOI:10.1021/ja100573d

Reference yield: 21.0%

vanadium(V) oxychloride (7727-18-6) + cyclohexylamine (108-91-8,157973-60-9) → cyclohexylimidovanadium(V)-trichloride (256385-95-2)

Guidance literature:

In petroleum ether; all manipulations under Ar; soln. of amine in petroleum ether added dropwise to soln. of VOCl3 at -78°C with stirring, then stirred for 30 min at this temp., allowed to warm to room temp. and stirred for 1 h; filtered, washed with petroleum ether, solvent evapd. in vac., residue sublimed at 120°C/1E-2 mbar; elem. anal.;

DOI:10.1515/znb-2001-0307

Reference yield: 57.0%

2,2-dimethylpropylidynephosphine (78129-68-7) + phenylacetylene (536-74-3) + cyclohexylimidovanadium(V)-trichloride (256385-95-2) → 1-cyclohexyl-3-tert-butyl-5-phenyl-1H-1,2-azaphosphol

Guidance literature:

In toluene; at -78 - 25 ℃; for 12h;

DOI:10.1515/znb-2003-0107

upstream raw materials:

vanadium(V) oxychloride

cyclohexylamine

Cyclohexyl isocyanate

Downstream raw materials:

V(N-cyclohexyl)Cl₂[2-(2,6-iPr₂C₆H₃)NCH₂(C₅H₄N)]